Heptalene Synthesis by Addition of Aryl Acetylenes to Azulenes
Publication type: Journal Article
Publication date: 2020-04-01
scimago Q4
wos Q4
SJR: 0.190
CiteScore: 1.3
Impact factor: 0.9
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
Abstract Aryl acetylenes bearing electron-withdrawing groups have been found that can add to azulenes and yield 1,2-substituted heptalenes. Theoretical studies of the reaction mechanism helped to design the candidate molecules that have then been tested in the synthetic work. New heptalenes are obtained by reacting methyl (4-nitrophenyl)propiolate with either 4,6,8-trimethylazulene or guaiazulene, as well as 3-(4-nitrophenyl)-2-propyn-1-ol with guaiazulene. This opens a new synthetic route to 1-aryl-substituted heptalenes.
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Briling K. R. et al. Heptalene Synthesis by Addition of Aryl Acetylenes to Azulenes // Russian Journal of Organic Chemistry. 2020. Vol. 56. No. 4. pp. 569-575.
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Briling K. R., Laikov D. Heptalene Synthesis by Addition of Aryl Acetylenes to Azulenes // Russian Journal of Organic Chemistry. 2020. Vol. 56. No. 4. pp. 569-575.
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TY - JOUR
DO - 10.1134/S1070428020040028
UR - https://link.springer.com/10.1134/S1070428020040028
TI - Heptalene Synthesis by Addition of Aryl Acetylenes to Azulenes
T2 - Russian Journal of Organic Chemistry
AU - Briling, K R
AU - Laikov, D.N.
PY - 2020
DA - 2020/04/01
PB - Pleiades Publishing
SP - 569-575
IS - 4
VL - 56
SN - 1070-4280
SN - 1608-3393
ER -
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BibTex (up to 50 authors)
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@article{2020_Briling,
author = {K R Briling and D.N. Laikov},
title = {Heptalene Synthesis by Addition of Aryl Acetylenes to Azulenes},
journal = {Russian Journal of Organic Chemistry},
year = {2020},
volume = {56},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://link.springer.com/10.1134/S1070428020040028},
number = {4},
pages = {569--575},
doi = {10.1134/S1070428020040028}
}
Cite this
MLA
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Briling, K. R., et al. “Heptalene Synthesis by Addition of Aryl Acetylenes to Azulenes.” Russian Journal of Organic Chemistry, vol. 56, no. 4, Apr. 2020, pp. 569-575. https://link.springer.com/10.1134/S1070428020040028.
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