Pleiades Publishing
Russian Journal of Organic Chemistry
,  volume 58 ,  issue 2 ,  pages 167-174

CuI and Copper Nanoparticles in the Catalytic Amination of 2-Halopyridines

Publication type: Journal Article
Publication date: 2022-02-01
Pleiades Publishing
scimago Q4
wos Q4
SJR: 0.190
CiteScore: 1.3
Impact factor: 0.9
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
The N-heteroarylation of n-octylamine and adamantane-containing amines with 2-iodopyridine and 2-bromopyridine and its fluorinated derivatives under the catalysis of CuI and copper nanoparticles in DMSO in the presence of various ligands was studied. 2-Isobutyrylcyclohexanone was found to be the most efficient ligand in the reactions catalyzed by CuI. In the reactions catalyzed by copper nanoparticles, 2-isobutyrylcyclohexanone or l-proline turned to be most active. The yields of the reactions catalyzed by copper nanoparticles were better than or equal to those in the CuI-catalyzed processes. The possibility of nanocatalyst recycling was studied, and its reuse in 6 cycles without loss of activity was demonstrated.
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GOST Copy
Kuliukhina D. S. et al. CuI and Copper Nanoparticles in the Catalytic Amination of 2-Halopyridines // Russian Journal of Organic Chemistry. 2022. Vol. 58. No. 2. pp. 167-174.
GOST all authors (up to 50) Copy
Kuliukhina D. S., Averin A. A., Panchenko S. P., Abel A. S., Savelyev E. N., Orlinson B. S., Novakov I. A., Correia C. R. D., Beletskaya I. P. CuI and Copper Nanoparticles in the Catalytic Amination of 2-Halopyridines // Russian Journal of Organic Chemistry. 2022. Vol. 58. No. 2. pp. 167-174.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1134/S1070428022020014
UR - https://doi.org/10.1134/S1070428022020014
TI - CuI and Copper Nanoparticles in the Catalytic Amination of 2-Halopyridines
T2 - Russian Journal of Organic Chemistry
AU - Kuliukhina, D S
AU - Averin, Alexey A
AU - Panchenko, S P
AU - Abel, Anton S
AU - Savelyev, E N
AU - Orlinson, Boris S
AU - Novakov, I A
AU - Correia, C R D
AU - Beletskaya, Irina P.
PY - 2022
DA - 2022/02/01
PB - Pleiades Publishing
SP - 167-174
IS - 2
VL - 58
SN - 1070-4280
SN - 1608-3393
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Kuliukhina,
author = {D S Kuliukhina and Alexey A Averin and S P Panchenko and Anton S Abel and E N Savelyev and Boris S Orlinson and I A Novakov and C R D Correia and Irina P. Beletskaya},
title = {CuI and Copper Nanoparticles in the Catalytic Amination of 2-Halopyridines},
journal = {Russian Journal of Organic Chemistry},
year = {2022},
volume = {58},
publisher = {Pleiades Publishing},
month = {feb},
url = {https://doi.org/10.1134/S1070428022020014},
number = {2},
pages = {167--174},
doi = {10.1134/S1070428022020014}
}
MLA
Cite this
MLA Copy
Kuliukhina, D. S., et al. “CuI and Copper Nanoparticles in the Catalytic Amination of 2-Halopyridines.” Russian Journal of Organic Chemistry, vol. 58, no. 2, Feb. 2022, pp. 167-174. https://doi.org/10.1134/S1070428022020014.