Glass Physics and Chemistry, volume 36, issue 4, pages 398-405
Phase transformations in sodium zinc silicate glasses containing PbS nanocrystals
Publication type: Journal Article
Publication date: 2010-08-01
Journal:
Glass Physics and Chemistry
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 0.7
ISSN: 10876596, 1608313X
Materials Chemistry
Ceramics and Composites
Condensed Matter Physics
Abstract
The phase composition and the kinetics of formation of the lead sulfide crystalline phase at the late stages of heat treatments of sodium zinc silicate glasses have been investigated using small-angle X-ray scattering and X-ray powder diffraction. It has been established that, after the completion of the precipitation of the PbS crystalline phase, the reaction PbS + ZnO = PbO + ZnS begins to proceed on the surface of nanocrystals. This reaction results in a decrease in the volume of the PbS phase and the precipitation of ZnS nanocrystals. The size effect has been revealed: PbS nanocrystals with a radius larger than approximately Å are stable, whereas nanocrystals with smaller sizes initiate the reaction PbS + ZnO = PbO + ZnS.
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Alekseeva I. P., Golubkov V., Onushchenko A. Phase transformations in sodium zinc silicate glasses containing PbS nanocrystals // Glass Physics and Chemistry. 2010. Vol. 36. No. 4. pp. 398-405.
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Alekseeva I. P., Golubkov V., Onushchenko A. Phase transformations in sodium zinc silicate glasses containing PbS nanocrystals // Glass Physics and Chemistry. 2010. Vol. 36. No. 4. pp. 398-405.
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TY - JOUR
DO - 10.1134/s1087659610040024
UR - https://doi.org/10.1134/s1087659610040024
TI - Phase transformations in sodium zinc silicate glasses containing PbS nanocrystals
T2 - Glass Physics and Chemistry
AU - Alekseeva, I P
AU - Golubkov, V.V.
AU - Onushchenko, A.A
PY - 2010
DA - 2010/08/01 00:00:00
PB - Pleiades Publishing
SP - 398-405
IS - 4
VL - 36
SN - 1087-6596
SN - 1608-313X
ER -
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@article{2010_Alekseeva,
author = {I P Alekseeva and V.V. Golubkov and A.A Onushchenko},
title = {Phase transformations in sodium zinc silicate glasses containing PbS nanocrystals},
journal = {Glass Physics and Chemistry},
year = {2010},
volume = {36},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134/s1087659610040024},
number = {4},
pages = {398--405},
doi = {10.1134/s1087659610040024}
}
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Alekseeva, I. P., et al. “Phase transformations in sodium zinc silicate glasses containing PbS nanocrystals.” Glass Physics and Chemistry, vol. 36, no. 4, Aug. 2010, pp. 398-405. https://doi.org/10.1134/s1087659610040024.