Syndiospecific polymerization of styrene in the presence of new titanium complexes with dialkanolamines: Titanocanes and bistitanocanes
Тип публикации: Journal Article
Дата публикации: 2010-04-30
scimago Q3
wos Q4
БС2
SJR: 0.234
CiteScore: 1.8
Impact factor: 1.0
ISSN: 15600904, 15556123
Materials Chemistry
Ceramics and Composites
Polymers and Plastics
Краткое описание
The syndiospecific polymerization of styrene is studied in the presence of titanium complexes with dialkanolamines—bistitanocanes and titanocane—activated by individual MAO or the combined cocatalyst MAO/TIBA. It is shown that these catalysts are more active and stereospecific after their activation with the combined cocatalyst ([TIBA]: [MAO] ≤ 0.13) than that in the case of the activation with MAO: The activities of the catalysts are ≤18 and 9 kg PS/(mol Ti h), and the syndiotacticities of PS are ≤76 and 60%, respectively. Polymers synthesized in the presence of bistitanocanes are characterized by M n ≤ 4.5 × 104 and T m ≤ 268°C and a narrow molecular-mass distribution (≤2.5).
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Vasilenko I. et al. Syndiospecific polymerization of styrene in the presence of new titanium complexes with dialkanolamines: Titanocanes and bistitanocanes // Polymer Science - Series B. 2010. Vol. 52. No. 3-4. pp. 136-143.
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Vasilenko I., Kostjuk S. V., Zaitsev K. V., Nedorezova P. M., Lemenovskii D. A., Karlov S. Syndiospecific polymerization of styrene in the presence of new titanium complexes with dialkanolamines: Titanocanes and bistitanocanes // Polymer Science - Series B. 2010. Vol. 52. No. 3-4. pp. 136-143.
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TY - JOUR
DO - 10.1134/S1560090410030036
UR - http://link.springer.com/10.1134/S1560090410030036
TI - Syndiospecific polymerization of styrene in the presence of new titanium complexes with dialkanolamines: Titanocanes and bistitanocanes
T2 - Polymer Science - Series B
AU - Vasilenko, I.V.
AU - Kostjuk, S V
AU - Zaitsev, K V
AU - Nedorezova, P M
AU - Lemenovskii, D A
AU - Karlov, S.S.
PY - 2010
DA - 2010/04/30
PB - Pleiades Publishing
SP - 136-143
IS - 3-4
VL - 52
SN - 1560-0904
SN - 1555-6123
ER -
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@article{2010_Vasilenko,
author = {I.V. Vasilenko and S V Kostjuk and K V Zaitsev and P M Nedorezova and D A Lemenovskii and S.S. Karlov},
title = {Syndiospecific polymerization of styrene in the presence of new titanium complexes with dialkanolamines: Titanocanes and bistitanocanes},
journal = {Polymer Science - Series B},
year = {2010},
volume = {52},
publisher = {Pleiades Publishing},
month = {apr},
url = {http://link.springer.com/10.1134/S1560090410030036},
number = {3-4},
pages = {136--143},
doi = {10.1134/S1560090410030036}
}
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Vasilenko, I.V., et al. “Syndiospecific polymerization of styrene in the presence of new titanium complexes with dialkanolamines: Titanocanes and bistitanocanes.” Polymer Science - Series B, vol. 52, no. 3-4, Apr. 2010, pp. 136-143. http://link.springer.com/10.1134/S1560090410030036.