volume 53 issue 7-8 pages 391-403

Controlled synthesis of polyacrylonitrile via reversible addition-fragmentation chain-transfer pseudoliving radical polymerization and its thermal behavior

E V Chernikova
Z A Poteryaeva
S S Belyaev
I E Nifantev
A V Shlyakhtin
Yu V Kostina
A S Cherevan
G.N. Bondarenko
E V Sivtsov
Publication typeJournal Article
Publication date2011-08-17
scimago Q3
wos Q4
SJR0.234
CiteScore1.8
Impact factor1.0
ISSN15600904, 15556123
Materials Chemistry
Ceramics and Composites
Polymers and Plastics
Abstract
The polymerization of acrylonitrile mediated by various trithiocarbonates as reversible addition-fragmentation chain-transfer agents is studied. It is shown that, when polymerization is performed in DMSO, a narrowly dispersed PAN with a controlled molecular mass can be prepared. The pseudoliving radical polymerization of acrylonitrile is conducted for the first time via the reversible addition-fragmentation chaintransfer mechanism in carbon dioxide at an increased pressure. The structure of the polymers is investigated via NMR and IR spectroscopy. As shown by DSC and IR pyrolysis, the thermal behavior of PAN is determined by its molecular mass, the width of the molecular-mass distribution, and the conditions of synthesis. The incorporation of functional groups of the reversible addition-fragmentation chain-transfer agent into a macromolecule changes the structure of the polyconjugated system and makes it possible to control the conditions of its formation.
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Chernikova E. V. et al. Controlled synthesis of polyacrylonitrile via reversible addition-fragmentation chain-transfer pseudoliving radical polymerization and its thermal behavior // Polymer Science - Series B. 2011. Vol. 53. No. 7-8. pp. 391-403.
GOST all authors (up to 50) Copy
Chernikova E. V., Poteryaeva Z. A., Belyaev S. S., Nifantev I. E., Shlyakhtin A. V., Kostina Yu. V., Cherevan A. S., Efimov M. N., Bondarenko G., Sivtsov E. V. Controlled synthesis of polyacrylonitrile via reversible addition-fragmentation chain-transfer pseudoliving radical polymerization and its thermal behavior // Polymer Science - Series B. 2011. Vol. 53. No. 7-8. pp. 391-403.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1134/S1560090411070013
UR - http://link.springer.com/10.1134/S1560090411070013
TI - Controlled synthesis of polyacrylonitrile via reversible addition-fragmentation chain-transfer pseudoliving radical polymerization and its thermal behavior
T2 - Polymer Science - Series B
AU - Chernikova, E V
AU - Poteryaeva, Z A
AU - Belyaev, S S
AU - Nifantev, I E
AU - Shlyakhtin, A V
AU - Kostina, Yu V
AU - Cherevan, A S
AU - Efimov, M N
AU - Bondarenko, G.N.
AU - Sivtsov, E V
PY - 2011
DA - 2011/08/17
PB - Pleiades Publishing
SP - 391-403
IS - 7-8
VL - 53
SN - 1560-0904
SN - 1555-6123
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2011_Chernikova,
author = {E V Chernikova and Z A Poteryaeva and S S Belyaev and I E Nifantev and A V Shlyakhtin and Yu V Kostina and A S Cherevan and M N Efimov and G.N. Bondarenko and E V Sivtsov},
title = {Controlled synthesis of polyacrylonitrile via reversible addition-fragmentation chain-transfer pseudoliving radical polymerization and its thermal behavior},
journal = {Polymer Science - Series B},
year = {2011},
volume = {53},
publisher = {Pleiades Publishing},
month = {aug},
url = {http://link.springer.com/10.1134/S1560090411070013},
number = {7-8},
pages = {391--403},
doi = {10.1134/S1560090411070013}
}
MLA
Cite this
MLA Copy
Chernikova, E. V., et al. “Controlled synthesis of polyacrylonitrile via reversible addition-fragmentation chain-transfer pseudoliving radical polymerization and its thermal behavior.” Polymer Science - Series B, vol. 53, no. 7-8, Aug. 2011, pp. 391-403. http://link.springer.com/10.1134/S1560090411070013.