Effects of synthesis conditions and the mechanism of homopolymerization of acrylonitrile on the thermal behavior of the resulting polymer
E V Chernikova
1
,
Z A Poteryaeva
1
,
A V Shlyakhtin
1
,
N I Prokopov
2
,
A Yu Gervald
2
,
A Yu Nikolaev
2
,
V R Duflot
3
,
E A Dubova
3
,
Yu V Kostina
4
,
A S Rodionov
4
,
M N Efimov
4
,
A S Cherevan
4
,
G.N. Bondarenko
4
Тип публикации: Journal Article
Дата публикации: 2013-01-01
scimago Q3
wos Q4
БС2
SJR: 0.234
CiteScore: 1.8
Impact factor: 1.0
ISSN: 15600904, 15556123
Materials Chemistry
Ceramics and Composites
Polymers and Plastics
Краткое описание
The effect of the conditions of polyacrylonitrile synthesis (nature of the solvent, homogeneity of the reaction medium, and type of initiation) on the conditions of formation of the polyconjugation system during the pyrolysis of polyacrylonitrile is studied. The controlled synthesis of polyacrylonitrile via radiation polymerization mediated by dibenzyl trithiocarbonate as a reversible addition-fragmentation chain-transfer agent at 25 and 80°C is performed for the first time. It is shown that the type of initiation in reversible addition-fragmentation chain-transfer polymerization (material initiation or radiolysis) strongly affects the structure of the formed polyconjugation system.
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Chernikova E. V. et al. Effects of synthesis conditions and the mechanism of homopolymerization of acrylonitrile on the thermal behavior of the resulting polymer // Polymer Science - Series B. 2013. Vol. 55. No. 1-2. pp. 1-13.
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Chernikova E. V., Poteryaeva Z. A., Shlyakhtin A. V., Prokopov N. I., Gervald A. Yu., Nikolaev A. Yu., Duflot V. R., Dubova E. A., Kostina Yu. V., Rodionov A. S., Efimov M. N., Cherevan A. S., Bondarenko G. Effects of synthesis conditions and the mechanism of homopolymerization of acrylonitrile on the thermal behavior of the resulting polymer // Polymer Science - Series B. 2013. Vol. 55. No. 1-2. pp. 1-13.
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TY - JOUR
DO - 10.1134/S1560090412110012
UR - http://link.springer.com/10.1134/S1560090412110012
TI - Effects of synthesis conditions and the mechanism of homopolymerization of acrylonitrile on the thermal behavior of the resulting polymer
T2 - Polymer Science - Series B
AU - Chernikova, E V
AU - Poteryaeva, Z A
AU - Shlyakhtin, A V
AU - Prokopov, N I
AU - Gervald, A Yu
AU - Nikolaev, A Yu
AU - Duflot, V R
AU - Dubova, E A
AU - Kostina, Yu V
AU - Rodionov, A S
AU - Efimov, M N
AU - Cherevan, A S
AU - Bondarenko, G.N.
PY - 2013
DA - 2013/01/01
PB - Pleiades Publishing
SP - 1-13
IS - 1-2
VL - 55
SN - 1560-0904
SN - 1555-6123
ER -
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@article{2013_Chernikova,
author = {E V Chernikova and Z A Poteryaeva and A V Shlyakhtin and N I Prokopov and A Yu Gervald and A Yu Nikolaev and V R Duflot and E A Dubova and Yu V Kostina and A S Rodionov and M N Efimov and A S Cherevan and G.N. Bondarenko},
title = {Effects of synthesis conditions and the mechanism of homopolymerization of acrylonitrile on the thermal behavior of the resulting polymer},
journal = {Polymer Science - Series B},
year = {2013},
volume = {55},
publisher = {Pleiades Publishing},
month = {jan},
url = {http://link.springer.com/10.1134/S1560090412110012},
number = {1-2},
pages = {1--13},
doi = {10.1134/S1560090412110012}
}
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MLA
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Chernikova, E. V., et al. “Effects of synthesis conditions and the mechanism of homopolymerization of acrylonitrile on the thermal behavior of the resulting polymer.” Polymer Science - Series B, vol. 55, no. 1-2, Jan. 2013, pp. 1-13. http://link.springer.com/10.1134/S1560090412110012.
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