Pleiades Publishing
Polymer Science - Series B
,  volume 55 ,  issue 7-8 ,  pages 453-459

Modified titanium-magnesium nanocatalysts in the polymerization of isoprene

Publication type: Journal Article
Publication date: 2013-07-01
Pleiades Publishing
scimago Q3
wos Q4
SJR: 0.234
CiteScore: 1.8
Impact factor: 1.0
ISSN: 15600904, 15556123
Materials Chemistry
Ceramics and Composites
Polymers and Plastics
Abstract
The polymerization of isoprene on titanium-magnesium nanocatalysts modified with electron-donor compounds based on organic phosphines and sulfides has been studied. It was shown that the catalyst modification makes it possible to increase the content of trans-1,4 units in polyisoprene up to 97% (according to the data of 1H NMR spectra). In the case of a catalyst modified with tributylphosphine, the effects of the phosphorus-to-titanium ratio on the polymerization kinetics, on the microstructure of trans-1,4-polyisoprene, and on the molecular mass of the polymer have been estimated.
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GOST Copy
Smetannikov O. V. et al. Modified titanium-magnesium nanocatalysts in the polymerization of isoprene // Polymer Science - Series B. 2013. Vol. 55. No. 7-8. pp. 453-459.
GOST all authors (up to 50) Copy
Smetannikov O. V., Tavtorkin A. N., Nifantev I. E., Chinova M. S., Gavrilenko I. F. Modified titanium-magnesium nanocatalysts in the polymerization of isoprene // Polymer Science - Series B. 2013. Vol. 55. No. 7-8. pp. 453-459.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S1560090413070051
UR - http://link.springer.com/10.1134/S1560090413070051
TI - Modified titanium-magnesium nanocatalysts in the polymerization of isoprene
T2 - Polymer Science - Series B
AU - Smetannikov, O V
AU - Tavtorkin, A N
AU - Nifantev, I E
AU - Chinova, M S
AU - Gavrilenko, I F
PY - 2013
DA - 2013/07/01
PB - Pleiades Publishing
SP - 453-459
IS - 7-8
VL - 55
SN - 1560-0904
SN - 1555-6123
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2013_Smetannikov,
author = {O V Smetannikov and A N Tavtorkin and I E Nifantev and M S Chinova and I F Gavrilenko},
title = {Modified titanium-magnesium nanocatalysts in the polymerization of isoprene},
journal = {Polymer Science - Series B},
year = {2013},
volume = {55},
publisher = {Pleiades Publishing},
month = {jul},
url = {http://link.springer.com/10.1134/S1560090413070051},
number = {7-8},
pages = {453--459},
doi = {10.1134/S1560090413070051}
}
MLA
Cite this
MLA Copy
Smetannikov, O. V., et al. “Modified titanium-magnesium nanocatalysts in the polymerization of isoprene.” Polymer Science - Series B, vol. 55, no. 7-8, Jul. 2013, pp. 453-459. http://link.springer.com/10.1134/S1560090413070051.
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