Polymer Science - Series B

, том 55 , издание 7-8 , страницы 453-459

Modified titanium-magnesium nanocatalysts in the polymerization of isoprene

O V Smetannikov ¹

A N Tavtorkin ¹

I E Nifantev ¹

M S Chinova ¹

I F Gavrilenko ¹

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Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia |

Тип публикации: Journal Article

Дата публикации: 2013-07-01

Pleiades Publishing

Polymer Science - Series B

scimago Q3

wos Q4

БС2

SJR: 0.234

CiteScore: 1.8

Impact factor: 1.0

ISSN: 15600904, 15556123

DOI: 10.1134/S1560090413070051

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Materials Chemistry

Ceramics and Composites

Polymers and Plastics

Краткое описание

The polymerization of isoprene on titanium-magnesium nanocatalysts modified with electron-donor compounds based on organic phosphines and sulfides has been studied. It was shown that the catalyst modification makes it possible to increase the content of trans-1,4 units in polyisoprene up to 97% (according to the data of 1H NMR spectra). In the case of a catalyst modified with tributylphosphine, the effects of the phosphorus-to-titanium ratio on the polymerization kinetics, on the microstructure of trans-1,4-polyisoprene, and on the molecular mass of the polymer have been estimated.

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Russian Journal of Applied Chemistry	Russian Journal of Applied Chemistry, 2, 33.33% Russian Journal of Applied Chemistry 2 публикации, 33.33%
Petroleum Chemistry	Petroleum Chemistry, 1, 16.67% Petroleum Chemistry 1 публикация, 16.67%
Высокомолекулярные соединения Б	Высокомолекулярные соединения Б, 1, 16.67% Высокомолекулярные соединения Б 1 публикация, 16.67%
Polymer Science - Series B	Polymer Science - Series B, 1, 16.67% Polymer Science - Series B 1 публикация, 16.67%
Kinetics and Catalysis	Kinetics and Catalysis, 1, 16.67% Kinetics and Catalysis 1 публикация, 16.67%
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Smetannikov O. V. et al. Modified titanium-magnesium nanocatalysts in the polymerization of isoprene // Polymer Science - Series B. 2013. Vol. 55. No. 7-8. pp. 453-459.

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Smetannikov O. V., Tavtorkin A. N., Nifantev I. E., Chinova M. S., Gavrilenko I. F. Modified titanium-magnesium nanocatalysts in the polymerization of isoprene // Polymer Science - Series B. 2013. Vol. 55. No. 7-8. pp. 453-459.

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TY - JOUR

DO - 10.1134/S1560090413070051

UR - http://link.springer.com/10.1134/S1560090413070051

TI - Modified titanium-magnesium nanocatalysts in the polymerization of isoprene

T2 - Polymer Science - Series B

AU - Smetannikov, O V

AU - Tavtorkin, A N

AU - Nifantev, I E

AU - Chinova, M S

AU - Gavrilenko, I F

PY - 2013

DA - 2013/07/01

PB - Pleiades Publishing

SP - 453-459

IS - 7-8

VL - 55

SN - 1560-0904

SN - 1555-6123

ER -

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@article{2013_Smetannikov,

author = {O V Smetannikov and A N Tavtorkin and I E Nifantev and M S Chinova and I F Gavrilenko},

title = {Modified titanium-magnesium nanocatalysts in the polymerization of isoprene},

journal = {Polymer Science - Series B},

year = {2013},

volume = {55},

publisher = {Pleiades Publishing},

month = {jul},

url = {http://link.springer.com/10.1134/S1560090413070051},

number = {7-8},

pages = {453--459},

doi = {10.1134/S1560090413070051}

}

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Smetannikov, O. V., et al. “Modified titanium-magnesium nanocatalysts in the polymerization of isoprene.” Polymer Science - Series B, vol. 55, no. 7-8, Jul. 2013, pp. 453-459. http://link.springer.com/10.1134/S1560090413070051.