Epoxy oligomers modified with epoxyphosphazenes
Тип публикации: Journal Article
Дата публикации: 2016-09-01
scimago Q3
wos Q4
БС2
SJR: 0.234
CiteScore: 1.8
Impact factor: 1.0
ISSN: 15600904, 15556123
Materials Chemistry
Ceramics and Composites
Polymers and Plastics
Краткое описание
Phosphazene-containing epoxy oligomers are obtained through a one-stage method via the interaction of hexachlorocyclotriphosphazene with an excess of diphenylolpropane in the medium of epichlorohydrin in the presence of a solid alkali. With the use of 31Р NMR and MALDI mass spectrometry, it is shown that the main components of the phosphazene fraction are penta- and tetra-aryloxysubstituted cyclotriphosphazene compounds with the corresponding numbers of epoxy groups. The maximum content of the phosphazene fraction in phosphazene-containing epoxy oligomers (~40 wt %) is attained at a hexachlorocyclotriphosphazene-to-diphenylolpropane molar ratio of 1: 8. Phosphazene-containing epoxy oligomers cured with isomethyltetrahydrophthalic anhydride have oxygen indexes of 26–28 and are self-extinguishing.
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Brigadnov K. A. et al. Epoxy oligomers modified with epoxyphosphazenes // Polymer Science - Series B. 2016. Vol. 58. No. 5. pp. 549-555.
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Brigadnov K. A., Bilichenko Yu. V., A. P. V., Borisov R. S., Gusev K. I., Rudakova T. A., Filatov S. N., Kireev V. V. Epoxy oligomers modified with epoxyphosphazenes // Polymer Science - Series B. 2016. Vol. 58. No. 5. pp. 549-555.
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TY - JOUR
DO - 10.1134/S1560090416050018
UR - https://doi.org/10.1134/S1560090416050018
TI - Epoxy oligomers modified with epoxyphosphazenes
T2 - Polymer Science - Series B
AU - Brigadnov, K A
AU - Bilichenko, Yu V
AU - A., Polyakov V.
AU - Borisov, R S
AU - Gusev, K I
AU - Rudakova, T A
AU - Filatov, S N
AU - Kireev, V. V.
PY - 2016
DA - 2016/09/01
PB - Pleiades Publishing
SP - 549-555
IS - 5
VL - 58
SN - 1560-0904
SN - 1555-6123
ER -
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@article{2016_Brigadnov,
author = {K A Brigadnov and Yu V Bilichenko and Polyakov V. A. and R S Borisov and K I Gusev and T A Rudakova and S N Filatov and V. V. Kireev},
title = {Epoxy oligomers modified with epoxyphosphazenes},
journal = {Polymer Science - Series B},
year = {2016},
volume = {58},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/S1560090416050018},
number = {5},
pages = {549--555},
doi = {10.1134/S1560090416050018}
}
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MLA
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Brigadnov, K. A., et al. “Epoxy oligomers modified with epoxyphosphazenes.” Polymer Science - Series B, vol. 58, no. 5, Sep. 2016, pp. 549-555. https://doi.org/10.1134/S1560090416050018.
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