Polymer Science - Series B

, volume 59 , issue 1 , pages 83-90

Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2-modified Fe3O4: Ferromagnetic oil sponges

P V Ivchenko ^{1, 2}

I E Nifantev ^{1, 2}

A A Vinogradov ¹

D P Krutko ²

G A Shandryuk ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia |

Department of Chemistry, Moscow State University, Moscow, Russia |

Publication type: Journal Article

Publication date: 2017-01-01

Pleiades Publishing

Polymer Science - Series B

scimago Q3

wos Q4

SJR: 0.234

CiteScore: 1.8

Impact factor: 1.0

ISSN: 15600904, 15556123

DOI: 10.1134/S1560090417010079

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Materials Chemistry

Ceramics and Composites

Polymers and Plastics

Abstract

The structure of zirconocene is determined experimentally. Zirconocene is found to catalyze effectively the copolymerization of α-olefins with nonconjugated dienes in the presence of minimal amounts of methylalumoxane as an organoaluminum activator. On the basis of a highly ferromagnetic carrier (a product of the reaction between Fe3O4 microparticles and Si(OEt)4), a deposited zirconocene catalyst is obtained. Using the latter, copolymers of α-olefins (1-hexene, 1-octene, and 1-decene) with 1,7-octadiene and 1,4- di(3-butenyl)benzene are synthesized. The obtained ferromagnetic copolymers demonstrate properties of effective absorbents of hydrocarbons, namely, oil sponges. A copolymer of 1-octene and 1,4-di(3-butenyl) benzene is found to possess the maximum adsorption capacity (up to 8) in the studied series.

Found

1 citation

Churakov Andrei

PhD in Chemistry

553 publications, 7 015 citations, 13 reviews

h-index: 37

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

1 citation

Ilyin Sergey

PhD in Chemistry

142 publications, 2 992 citations, 623 reviews

h-index: 34

A.V. Topchiev Institute of Petrochemical Synthesis RAS

High molecular weight compounds

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Ivchenko P. V. et al. Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2-modified Fe3O4: Ferromagnetic oil sponges // Polymer Science - Series B. 2017. Vol. 59. No. 1. pp. 83-90.

GOST all authors (up to 50) Copy

Ivchenko P. V., Nifantev I. E., Vinogradov A. A., Krutko D. P., Shandryuk G. A. Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2-modified Fe3O4: Ferromagnetic oil sponges // Polymer Science - Series B. 2017. Vol. 59. No. 1. pp. 83-90.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1134/S1560090417010079

UR - http://link.springer.com/10.1134/S1560090417010079

TI - Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2-modified Fe3O4: Ferromagnetic oil sponges

T2 - Polymer Science - Series B

AU - Ivchenko, P V

AU - Nifantev, I E

AU - Vinogradov, A A

AU - Krutko, D P

AU - Shandryuk, G A

PY - 2017

DA - 2017/01/01

PB - Pleiades Publishing

SP - 83-90

IS - 1

VL - 59

SN - 1560-0904

SN - 1555-6123

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2017_Ivchenko,

author = {P V Ivchenko and I E Nifantev and A A Vinogradov and D P Krutko and G A Shandryuk},

title = {Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2-modified Fe3O4: Ferromagnetic oil sponges},

journal = {Polymer Science - Series B},

year = {2017},

volume = {59},

publisher = {Pleiades Publishing},

month = {jan},

url = {http://link.springer.com/10.1134/S1560090417010079},

number = {1},

pages = {83--90},

doi = {10.1134/S1560090417010079}

}

MLA

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MLA Copy

Ivchenko, P. V., et al. “Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2-modified Fe3O4: Ferromagnetic oil sponges.” Polymer Science - Series B, vol. 59, no. 1, Jan. 2017, pp. 83-90. http://link.springer.com/10.1134/S1560090417010079.

Publisher

Pleiades Publishing

Journal

Polymer Science - Series B

scimago Q3

wos Q4

SJR

0.234

CiteScore

1.8

Impact factor

1.0

ISSN

15600904 (Print)

15556123 (Electronic)

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