Polymer Science - Series B, volume 59, issue 1, pages 83-90
Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2 -modified Fe3 O4 : Ferromagnetic oil sponges
Publication type: Journal Article
Publication date: 2017-01-01
Journal:
Polymer Science - Series B
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor: 1.2
ISSN: 15600904, 15556123
Materials Chemistry
Ceramics and Composites
Polymers and Plastics
Abstract
The structure of zirconocene is determined experimentally. Zirconocene is found to catalyze effectively the copolymerization of α-olefins with nonconjugated dienes in the presence of minimal amounts of methylalumoxane as an organoaluminum activator. On the basis of a highly ferromagnetic carrier (a product of the reaction between Fe3O4 microparticles and Si(OEt)4), a deposited zirconocene catalyst is obtained. Using the latter, copolymers of α-olefins (1-hexene, 1-octene, and 1-decene) with 1,7-octadiene and 1,4- di(3-butenyl)benzene are synthesized. The obtained ferromagnetic copolymers demonstrate properties of effective absorbents of hydrocarbons, namely, oil sponges. A copolymer of 1-octene and 1,4-di(3-butenyl) benzene is found to possess the maximum adsorption capacity (up to 8) in the studied series.
Citations by journals
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1
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Applied Catalysis A: General
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Pure and Applied Chemistry
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Citations by publishers
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1
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2 publications, 40%
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1 publication, 20%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 20%
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Walter de Gruyter
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Walter de Gruyter
1 publication, 20%
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1
2
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Ivchenko P. V. et al. Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2-modified Fe3O4: Ferromagnetic oil sponges // Polymer Science - Series B. 2017. Vol. 59. No. 1. pp. 83-90.
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Ivchenko P. V., Nifantev I. E., Vinogradov A. A., Krutko D. P., Shandryuk G. A. Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2-modified Fe3O4: Ferromagnetic oil sponges // Polymer Science - Series B. 2017. Vol. 59. No. 1. pp. 83-90.
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TY - JOUR
DO - 10.1134/S1560090417010079
UR - https://doi.org/10.1134%2FS1560090417010079
TI - Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2-modified Fe3O4: Ferromagnetic oil sponges
T2 - Polymer Science - Series B
AU - Ivchenko, P V
AU - Nifantev, I E
AU - Vinogradov, A A
AU - Krutko, D P
AU - Shandryuk, G A
PY - 2017
DA - 2017/01/01 00:00:00
PB - Pleiades Publishing
SP - 83-90
IS - 1
VL - 59
SN - 1560-0904
SN - 1555-6123
ER -
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@article{2017_Ivchenko,
author = {P V Ivchenko and I E Nifantev and A A Vinogradov and D P Krutko and G A Shandryuk},
title = {Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2-modified Fe3O4: Ferromagnetic oil sponges},
journal = {Polymer Science - Series B},
year = {2017},
volume = {59},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1134%2FS1560090417010079},
number = {1},
pages = {83--90},
doi = {10.1134/S1560090417010079}
}
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MLA
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Ivchenko, P. V., et al. “Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2-modified Fe3O4: Ferromagnetic oil sponges.” Polymer Science - Series B, vol. 59, no. 1, Jan. 2017, pp. 83-90. https://doi.org/10.1134%2FS1560090417010079.