volume 59 issue 2 pages 147-156

Polymerization of trimethylene carbonate and lactones in the presence of magnesium monoionolate: A comparative theoretical and experimental study

Publication typeJournal Article
Publication date2017-03-01
scimago Q3
wos Q4
SJR0.234
CiteScore1.8
Impact factor1.0
ISSN15600904, 15556123
Materials Chemistry
Ceramics and Composites
Polymers and Plastics
Abstract
Using quantum-chemical calculations (DFT, program Priroda), the formation of a catalyst species on the basis of magnesium complexes with 2,6-di-tert-butyl-4-methylphenol is discussed. A comparative theoretical and experimental study of the ring-opening polymerization of trimethylene carbonate, 1,4-dioxanone, δ-valerolactone, and e-caprolactone in the presence of the monoionolate magnesium complex is performed. It is shown that the calculated values of activation barriers correlate with the observed order of activity of cyclic esters. The maximum rate of polymerization is exhibited by trimethylene carbonate.
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Nifantev I. E. et al. Polymerization of trimethylene carbonate and lactones in the presence of magnesium monoionolate: A comparative theoretical and experimental study // Polymer Science - Series B. 2017. Vol. 59. No. 2. pp. 147-156.
GOST all authors (up to 50) Copy
Nifantev I. E., Ivchenko P. V., Shlyakhtin A. V., Ivanyuk A. V. Polymerization of trimethylene carbonate and lactones in the presence of magnesium monoionolate: A comparative theoretical and experimental study // Polymer Science - Series B. 2017. Vol. 59. No. 2. pp. 147-156.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S1560090417020075
UR - http://link.springer.com/10.1134/S1560090417020075
TI - Polymerization of trimethylene carbonate and lactones in the presence of magnesium monoionolate: A comparative theoretical and experimental study
T2 - Polymer Science - Series B
AU - Nifantev, I E
AU - Ivchenko, P V
AU - Shlyakhtin, A V
AU - Ivanyuk, A V
PY - 2017
DA - 2017/03/01
PB - Pleiades Publishing
SP - 147-156
IS - 2
VL - 59
SN - 1560-0904
SN - 1555-6123
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2017_Nifantev,
author = {I E Nifantev and P V Ivchenko and A V Shlyakhtin and A V Ivanyuk},
title = {Polymerization of trimethylene carbonate and lactones in the presence of magnesium monoionolate: A comparative theoretical and experimental study},
journal = {Polymer Science - Series B},
year = {2017},
volume = {59},
publisher = {Pleiades Publishing},
month = {mar},
url = {http://link.springer.com/10.1134/S1560090417020075},
number = {2},
pages = {147--156},
doi = {10.1134/S1560090417020075}
}
MLA
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MLA Copy
Nifantev, I. E., et al. “Polymerization of trimethylene carbonate and lactones in the presence of magnesium monoionolate: A comparative theoretical and experimental study.” Polymer Science - Series B, vol. 59, no. 2, Mar. 2017, pp. 147-156. http://link.springer.com/10.1134/S1560090417020075.