volume 53 issue 1 pages 61-67

Formation of Metal-Polymer Hybrid Nanostructures during Radiation-Induced Reduction of Metal Ions in Poly(acrylic acid)-Poly(ethylenimine) Complexes

A A Zezin
S S Abramchuk
V K Ivanchenko
N A Shmakova
V.I. Shvedunov
Publication typeJournal Article
Publication date2011-09-06
scimago Q3
wos Q4
SJR0.322
CiteScore2.6
Impact factor1.1
ISSN18112382, 1555614X
Materials Chemistry
General Chemistry
Polymers and Plastics
Abstract
The formation of nanoparticles during the radiation-induced chemical reduction of silver ions, copper ions, and nickel ions in films based on poly(acrylic acid)-poly(ethylenimine) complexes are studied via electron microscopy. This approach allows preparation of composites containing nanoparticles that are randomly distributed in the polymer matrix and materials with a regular spatial distribution of nanoparticles across the film thickness and in subsurface layers. The structure of metal-polymer hybrid materials is dependent on the irradiation conditions, the type of reduced metal ions, and their initial content in polymer matrices. The ratio between the rate of nucleation and the rate of growth of nanoparticles in the matrices of interpolyelectrolyte complexes depends on the intensity of the absorbed dose and on the mechanisms of reduction of metal ions and formation of clusters. The IR spectroscopic studies reveal the effect of nanoparticles on the chemical structure of the polymer matrix.
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GOST Copy
Zezin A. A. et al. Formation of Metal-Polymer Hybrid Nanostructures during Radiation-Induced Reduction of Metal Ions in Poly(acrylic acid)-Poly(ethylenimine) Complexes // Polymer Science - Series C. 2011. Vol. 53. No. 1. pp. 61-67.
GOST all authors (up to 50) Copy
Zezin A. A., Feldman V. I., Abramchuk S. S., Ivanchenko V. K., Zezina E. A., Shmakova N. A., Shvedunov V. Formation of Metal-Polymer Hybrid Nanostructures during Radiation-Induced Reduction of Metal Ions in Poly(acrylic acid)-Poly(ethylenimine) Complexes // Polymer Science - Series C. 2011. Vol. 53. No. 1. pp. 61-67.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1134/S1811238211060038
UR - http://link.springer.com/10.1134/S1811238211060038
TI - Formation of Metal-Polymer Hybrid Nanostructures during Radiation-Induced Reduction of Metal Ions in Poly(acrylic acid)-Poly(ethylenimine) Complexes
T2 - Polymer Science - Series C
AU - Zezin, A A
AU - Feldman, V I
AU - Abramchuk, S S
AU - Ivanchenko, V K
AU - Zezina, E A
AU - Shmakova, N A
AU - Shvedunov, V.I.
PY - 2011
DA - 2011/09/06
PB - Pleiades Publishing
SP - 61-67
IS - 1
VL - 53
SN - 1811-2382
SN - 1555-614X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2011_Zezin,
author = {A A Zezin and V I Feldman and S S Abramchuk and V K Ivanchenko and E A Zezina and N A Shmakova and V.I. Shvedunov},
title = {Formation of Metal-Polymer Hybrid Nanostructures during Radiation-Induced Reduction of Metal Ions in Poly(acrylic acid)-Poly(ethylenimine) Complexes},
journal = {Polymer Science - Series C},
year = {2011},
volume = {53},
publisher = {Pleiades Publishing},
month = {sep},
url = {http://link.springer.com/10.1134/S1811238211060038},
number = {1},
pages = {61--67},
doi = {10.1134/S1811238211060038}
}
MLA
Cite this
MLA Copy
Zezin, A. A., et al. “Formation of Metal-Polymer Hybrid Nanostructures during Radiation-Induced Reduction of Metal Ions in Poly(acrylic acid)-Poly(ethylenimine) Complexes.” Polymer Science - Series C, vol. 53, no. 1, Sep. 2011, pp. 61-67. http://link.springer.com/10.1134/S1811238211060038.