Polymer Science - Series C, volume 61, issue 1, pages 31-40
Promising Catalytic Processes of Dicyclopentadiene Metathesis Polymerization to Obtain a New Class of Polymeric and Polymer–Composite Materials
1
OOO Joint Research and Development Center, Moscow, Russia
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Publication type: Journal Article
Publication date: 2019-09-01
Journal:
Polymer Science - Series C
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 2.2
ISSN: 18112382, 1555614X
Materials Chemistry
General Chemistry
Polymers and Plastics
Abstract
A lineup of highly efficient ruthenium catalysts with N-containing substituents in the benzylidene ligand is developed that differ in the rate of initiation of dicyclopentadiene metathesis polymerization. The choice of the optimal catalyst makes it possible to control the lifetime of the monomer–catalyst reaction mixture in a wide range, which makes the use of various technologies effective for the production of polymer and composite materials. The new catalysts have been used to design a series of innovative polymer and polymer-composite materials with a polymer matrix based on a finished monomer, dicyclopentadiene, which is a raw material of the petrochemical industry. The polymeric materials are distinguished by a unique combination of high mechanical properties and good thermal stability in a wide temperature range (from –60 to +320°C), which allows their use in various climatic zones. Composites with a matrix based on polydicyclopentadiene are not inferior to commercially available counterparts based on epoxy and polyester resins and even surpass them in a number of parameters.
Top-30
Citations by journals
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1
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Polymers
1 publication, 50%
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Russian Chemical Reviews
1 publication, 50%
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1
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Citations by publishers
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1
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 50%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 50%
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1
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Afanas'ev V., Yumasheva T. M., Bespalova N. Promising Catalytic Processes of Dicyclopentadiene Metathesis Polymerization to Obtain a New Class of Polymeric and Polymer–Composite Materials // Polymer Science - Series C. 2019. Vol. 61. No. 1. pp. 31-40.
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Afanas'ev V., Yumasheva T. M., Bespalova N. Promising Catalytic Processes of Dicyclopentadiene Metathesis Polymerization to Obtain a New Class of Polymeric and Polymer–Composite Materials // Polymer Science - Series C. 2019. Vol. 61. No. 1. pp. 31-40.
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TY - JOUR
DO - 10.1134/s1811238219010016
UR - https://doi.org/10.1134/s1811238219010016
TI - Promising Catalytic Processes of Dicyclopentadiene Metathesis Polymerization to Obtain a New Class of Polymeric and Polymer–Composite Materials
T2 - Polymer Science - Series C
AU - Afanas'ev, V.V.
AU - Yumasheva, T M
AU - Bespalova, N.B.
PY - 2019
DA - 2019/09/01 00:00:00
PB - Pleiades Publishing
SP - 31-40
IS - 1
VL - 61
SN - 1811-2382
SN - 1555-614X
ER -
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@article{2019_Afanas'ev,
author = {V.V. Afanas'ev and T M Yumasheva and N.B. Bespalova},
title = {Promising Catalytic Processes of Dicyclopentadiene Metathesis Polymerization to Obtain a New Class of Polymeric and Polymer–Composite Materials},
journal = {Polymer Science - Series C},
year = {2019},
volume = {61},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/s1811238219010016},
number = {1},
pages = {31--40},
doi = {10.1134/s1811238219010016}
}
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Afanas'ev, V.V., et al. “Promising Catalytic Processes of Dicyclopentadiene Metathesis Polymerization to Obtain a New Class of Polymeric and Polymer–Composite Materials.” Polymer Science - Series C, vol. 61, no. 1, Sep. 2019, pp. 31-40. https://doi.org/10.1134/s1811238219010016.