Pleiades Publishing
Polymer Science - Series C
,  volume 63 ,  issue 1 ,  pages 11-28

Kinetic Features of the Radical Polymerization of Methyl Methacrylate under Conditions of Nitroxide-Mediated Reversible Inhibition

Publication type: Journal Article
Publication date: 2021-01-01
Pleiades Publishing
scimago Q3
wos Q4
SJR: 0.322
CiteScore: 2.6
Impact factor: 1.1
ISSN: 18112382, 1555614X
Materials Chemistry
General Chemistry
Polymers and Plastics
Abstract
This review summarizes our and published data on the kinetics and mechanism of controlled radical polymerization of methacrylates mediated by nitroxide radicals. The reasons influencing the possibility or impossibility of the realization of radical polymerization of methyl methacrylate in the mode of reversible inhibition are analyzed. The main factors determining the specificity of the nitroxide-mediated polymerization of methacrylates are the interaction of nitroxides with growing radicals by the disproportionation mechanism, the Fischer hypereffect, a high rate of reinitiation, and an abnormally low rate of reversible termination.
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GOST Copy
Zaremski M. Y., Odintsova V. V. Kinetic Features of the Radical Polymerization of Methyl Methacrylate under Conditions of Nitroxide-Mediated Reversible Inhibition // Polymer Science - Series C. 2021. Vol. 63. No. 1. pp. 11-28.
GOST all authors (up to 50) Copy
Zaremski M. Y., Odintsova V. V. Kinetic Features of the Radical Polymerization of Methyl Methacrylate under Conditions of Nitroxide-Mediated Reversible Inhibition // Polymer Science - Series C. 2021. Vol. 63. No. 1. pp. 11-28.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S1811238221010069
UR - https://link.springer.com/10.1134/S1811238221010069
TI - Kinetic Features of the Radical Polymerization of Methyl Methacrylate under Conditions of Nitroxide-Mediated Reversible Inhibition
T2 - Polymer Science - Series C
AU - Zaremski, M. Yu.
AU - Odintsova, V V
PY - 2021
DA - 2021/01/01
PB - Pleiades Publishing
SP - 11-28
IS - 1
VL - 63
SN - 1811-2382
SN - 1555-614X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Zaremski,
author = {M. Yu. Zaremski and V V Odintsova},
title = {Kinetic Features of the Radical Polymerization of Methyl Methacrylate under Conditions of Nitroxide-Mediated Reversible Inhibition},
journal = {Polymer Science - Series C},
year = {2021},
volume = {63},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://link.springer.com/10.1134/S1811238221010069},
number = {1},
pages = {11--28},
doi = {10.1134/S1811238221010069}
}
MLA
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MLA Copy
Zaremski, M. Yu., and V V Odintsova. “Kinetic Features of the Radical Polymerization of Methyl Methacrylate under Conditions of Nitroxide-Mediated Reversible Inhibition.” Polymer Science - Series C, vol. 63, no. 1, Jan. 2021, pp. 11-28. https://link.springer.com/10.1134/S1811238221010069.