Dispersion copolymerization of methyl methacrylate and styrene in supercritical carbon dioxide
Publication type: Journal Article
Publication date: 2010-12-01
scimago Q4
SJR: 0.244
CiteScore: 2.6
Impact factor: —
ISSN: 19907931, 19907923
Physical and Theoretical Chemistry
Abstract
A method for producing finely dispersed powders of methyl methacrylate (MMA)-styrene copolymer by radical polymerization in a supercritical carbon dioxide medium (SC-CO2) was proposed, studied, and experimentally implemented. The dispersing agent (surfactant), which made it possible to obtain nearly monodisperse size distribution of polymer particles, was poly(dimethylsiloxane methacrylate), a SC-CO2-soluble substance. The copolymer, synthesized with a molecular mass of Mw ∼ 36000 in the form of spherical particles with a characteristic size of ∼1 μm, exhibited a higher thermal stability as compared to poly(methyl methacrylate) with a similar molecular mass. Varying the percentage ratio between MMA and styrene monomers, it was possible effectively control the integral hydrophobicity and physicomechanical characteristics of the methacrylate-styrene copolymer.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
Russian Journal of Physical Chemistry B
2 publications, 40%
|
|
|
Journal of Supercritical Fluids
1 publication, 20%
|
|
|
Polymer International
1 publication, 20%
|
|
|
1
2
|
Publishers
|
1
2
|
|
|
Elsevier
2 publications, 40%
|
|
|
Pleiades Publishing
2 publications, 40%
|
|
|
Wiley
1 publication, 20%
|
|
|
1
2
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
5
Total citations:
5
Citations from 2025:
0
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Timashev P. S. et al. Dispersion copolymerization of methyl methacrylate and styrene in supercritical carbon dioxide // Russian Journal of Physical Chemistry B. 2010. Vol. 4. No. 7. pp. 1158-1163.
GOST all authors (up to 50)
Copy
Timashev P. S., Krotova L. I., Lemenovskii D. A., Popov V. Dispersion copolymerization of methyl methacrylate and styrene in supercritical carbon dioxide // Russian Journal of Physical Chemistry B. 2010. Vol. 4. No. 7. pp. 1158-1163.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S199079311007016X
UR - http://link.springer.com/10.1134/S199079311007016X
TI - Dispersion copolymerization of methyl methacrylate and styrene in supercritical carbon dioxide
T2 - Russian Journal of Physical Chemistry B
AU - Timashev, P S
AU - Krotova, L I
AU - Lemenovskii, D A
AU - Popov, V.K.
PY - 2010
DA - 2010/12/01
PB - Pleiades Publishing
SP - 1158-1163
IS - 7
VL - 4
SN - 1990-7931
SN - 1990-7923
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2010_Timashev,
author = {P S Timashev and L I Krotova and D A Lemenovskii and V.K. Popov},
title = {Dispersion copolymerization of methyl methacrylate and styrene in supercritical carbon dioxide},
journal = {Russian Journal of Physical Chemistry B},
year = {2010},
volume = {4},
publisher = {Pleiades Publishing},
month = {dec},
url = {http://link.springer.com/10.1134/S199079311007016X},
number = {7},
pages = {1158--1163},
doi = {10.1134/S199079311007016X}
}
Cite this
MLA
Copy
Timashev, P. S., et al. “Dispersion copolymerization of methyl methacrylate and styrene in supercritical carbon dioxide.” Russian Journal of Physical Chemistry B, vol. 4, no. 7, Dec. 2010, pp. 1158-1163. http://link.springer.com/10.1134/S199079311007016X.