Carboxylation of aromatic compounds in a supercritical carbon dioxide medium
Publication type: Journal Article
Publication date: 2012-12-01
scimago Q4
SJR: 0.244
CiteScore: 2.6
Impact factor: —
ISSN: 19907931, 19907923
Physical and Theoretical Chemistry
Abstract
The reaction of direct carboxylation of benzene and its derivatives PhX (X = Me, Br, Ph, OPh, OMe), as well as mesitylene, durene, and ferrocene, in a supercritical CO2 medium in the presence of various Lewis acids (AlCl3, FeCl3, ZrCl4, and ZnCl2) is studied. It is shown that, in all cases, secondary reactions proceed faster than the primary reaction of carboxylic acid formation. For the thoroughly studied AlCl3-CO2toluene system, optimal conditions of the formation of n-toluic acid are determined. For the AlCl3-CO2-benzene system, as an example, quantum-chemical calculations of the characteristics of the allowed pathways of the carboxylation reaction are performed.
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Shlyakhtin A. V. et al. Carboxylation of aromatic compounds in a supercritical carbon dioxide medium // Russian Journal of Physical Chemistry B. 2012. Vol. 6. No. 7. pp. 818-826.
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Shlyakhtin A. V., Vatsadze S. Z., Krutko D. P., Lemenovskii D. A., Zabalov M. V. Carboxylation of aromatic compounds in a supercritical carbon dioxide medium // Russian Journal of Physical Chemistry B. 2012. Vol. 6. No. 7. pp. 818-826.
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RIS
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TY - JOUR
DO - 10.1134/S199079311207007X
UR - http://link.springer.com/10.1134/S199079311207007X
TI - Carboxylation of aromatic compounds in a supercritical carbon dioxide medium
T2 - Russian Journal of Physical Chemistry B
AU - Shlyakhtin, A V
AU - Vatsadze, S. Z.
AU - Krutko, D P
AU - Lemenovskii, D A
AU - Zabalov, M V
PY - 2012
DA - 2012/12/01
PB - Pleiades Publishing
SP - 818-826
IS - 7
VL - 6
SN - 1990-7931
SN - 1990-7923
ER -
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BibTex (up to 50 authors)
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@article{2012_Shlyakhtin,
author = {A V Shlyakhtin and S. Z. Vatsadze and D P Krutko and D A Lemenovskii and M V Zabalov},
title = {Carboxylation of aromatic compounds in a supercritical carbon dioxide medium},
journal = {Russian Journal of Physical Chemistry B},
year = {2012},
volume = {6},
publisher = {Pleiades Publishing},
month = {dec},
url = {http://link.springer.com/10.1134/S199079311207007X},
number = {7},
pages = {818--826},
doi = {10.1134/S199079311207007X}
}
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MLA
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Shlyakhtin, A. V., et al. “Carboxylation of aromatic compounds in a supercritical carbon dioxide medium.” Russian Journal of Physical Chemistry B, vol. 6, no. 7, Dec. 2012, pp. 818-826. http://link.springer.com/10.1134/S199079311207007X.