Transformation of alkylbenzenes in an oxidizing medium on H-ZSM-5 catalyst under supercritical conditions
Publication type: Journal Article
Publication date: 2016-12-01
scimago Q4
SJR: 0.244
CiteScore: 2.6
Impact factor: —
ISSN: 19907931, 19907923
Physical and Theoretical Chemistry
Abstract
Reactions of the substituted benzenes toluene, p-xylene, fluorobenzene, phenol, cumene and styrene with nitrous oxide as an oxidant on H-ZSM-5 catalyst under supercritical conditions at 345–420°C and 70–150 atm were studied. It is shown that the products of disproportionation, isomerization and condensation that do not contain oxygen form predominantly. Only in the oxidation of toluene does the selectivity to the oxidation product (cresols) reach 35%. The yield of corresponding phenols in the oxidation of alkyl-, hydroxy- and fluorobenzenes is negligible. The double bond conjugated with the π-system of benzene rings (styrene), as well as the presence of branched alkyl substituents (in cumene) and hydroxyl-group (in phenol) hinder the formation of benzene ring oxidation products.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
|
|
|
Russian Chemical Reviews
1 publication, 25%
|
|
|
Russian Journal of Physical Chemistry B
1 publication, 25%
|
|
|
Journal of Supercritical Fluids
1 publication, 25%
|
|
|
Mendeleev Communications
1 publication, 25%
|
|
|
1
|
Publishers
|
1
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 25%
|
|
|
Pleiades Publishing
1 publication, 25%
|
|
|
Elsevier
1 publication, 25%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 25%
|
|
|
1
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
4
Total citations:
4
Citations from 2025:
1
(25%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Kustov A. et al. Transformation of alkylbenzenes in an oxidizing medium on H-ZSM-5 catalyst under supercritical conditions // Russian Journal of Physical Chemistry B. 2016. Vol. 10. No. 7. pp. 1131-1137.
GOST all authors (up to 50)
Copy
Kustov A., Kalenchuk A. N., Lunin V. V., Koklin A., Bogdan V. I. Transformation of alkylbenzenes in an oxidizing medium on H-ZSM-5 catalyst under supercritical conditions // Russian Journal of Physical Chemistry B. 2016. Vol. 10. No. 7. pp. 1131-1137.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S1990793116070113
UR - https://doi.org/10.1134/S1990793116070113
TI - Transformation of alkylbenzenes in an oxidizing medium on H-ZSM-5 catalyst under supercritical conditions
T2 - Russian Journal of Physical Chemistry B
AU - Kustov, A.L.
AU - Kalenchuk, A N
AU - Lunin, V. V.
AU - Koklin, A.E.
AU - Bogdan, V. I.
PY - 2016
DA - 2016/12/01
PB - Pleiades Publishing
SP - 1131-1137
IS - 7
VL - 10
SN - 1990-7931
SN - 1990-7923
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Kustov,
author = {A.L. Kustov and A N Kalenchuk and V. V. Lunin and A.E. Koklin and V. I. Bogdan},
title = {Transformation of alkylbenzenes in an oxidizing medium on H-ZSM-5 catalyst under supercritical conditions},
journal = {Russian Journal of Physical Chemistry B},
year = {2016},
volume = {10},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/S1990793116070113},
number = {7},
pages = {1131--1137},
doi = {10.1134/S1990793116070113}
}
Cite this
MLA
Copy
Kustov, A.L., et al. “Transformation of alkylbenzenes in an oxidizing medium on H-ZSM-5 catalyst under supercritical conditions.” Russian Journal of Physical Chemistry B, vol. 10, no. 7, Dec. 2016, pp. 1131-1137. https://doi.org/10.1134/S1990793116070113.