Russian Journal of Physical Chemistry B, volume 15, issue 7, pages 1157-1165
Impregnation of Polymethyl Methacrylate with Carbamazepine in Supercritical Carbon Dioxide
Publication type: Journal Article
Publication date: 2021-12-01
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor: 1.4
ISSN: 19907931, 19907923
Physical and Theoretical Chemistry
Abstract
Two polymethyl methacrylate (PMMA) samples are impregnated with carbamazepine (CBZ) in a supercritical CO2 (SC-CO2) medium at temperatures of 75 and 105°C and a constant CO2 density of 1.3 of its critical value. Before that, to determine the kinetic parameters of CO2 sorption by the polymer matrix, high-pressure NMR spectroscopy is used. By Raman spectroscopy, it is established that both polymethyl methacrylate samples contain carbamazepine, whose concentration in the polymer is 2.7 times higher for the case of impregnation at 105°C compared to that at 75°C. In addition, it is shown that, in the process of impregnation, CBZ is not crystallized in the polymer matrix, but rather forms a solution in PMMA, which, in turn, agrees well with the results of the X-ray phase analysis. The difference in the conformations of CBZ molecules in the polymer matrices impregnated at two different temperatures is established.
Citations by journals
1
|
|
Russian Journal of Physical Chemistry B
|
Russian Journal of Physical Chemistry B
1 publication, 14.29%
|
Journal of Molecular Liquids
|
Journal of Molecular Liquids
1 publication, 14.29%
|
International Journal of Molecular Sciences
|
International Journal of Molecular Sciences
1 publication, 14.29%
|
Journal of Supercritical Fluids
|
Journal of Supercritical Fluids
1 publication, 14.29%
|
Journal of CO2 Utilization
|
Journal of CO2 Utilization
1 publication, 14.29%
|
Materials Chemistry and Physics
|
Materials Chemistry and Physics
1 publication, 14.29%
|
Industrial & Engineering Chemistry Research
|
Industrial & Engineering Chemistry Research
1 publication, 14.29%
|
1
|
Citations by publishers
1
2
3
4
|
|
Elsevier
|
Elsevier
4 publications, 57.14%
|
Pleiades Publishing
|
Pleiades Publishing
1 publication, 14.29%
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 14.29%
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
1 publication, 14.29%
|
1
2
3
4
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023,2024],"ids":[0,0,0,0],"codes":[0,0,0,0],"imageUrls":["","","",""],"datasets":[{"label":"Citations number","data":[1,2,3,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["14.29","28.57","42.86","14.29"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Russian Journal of Physical Chemistry B","Journal of Molecular Liquids","International Journal of Molecular Sciences","Journal of Supercritical Fluids","Journal of CO2 Utilization","Materials Chemistry and Physics","Industrial & Engineering Chemistry Research"],"ids":[16359,13597,14627,12280,21077,12041,12141],"codes":[0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp"],"datasets":[{"label":"","data":[1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[14.29,14.29,14.29,14.29,14.29,14.29,14.29],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Pleiades Publishing","Multidisciplinary Digital Publishing Institute (MDPI)","American Chemical Society (ACS)"],"ids":[17,101,202,40],"codes":[0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp"],"datasets":[{"label":"","data":[4,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[57.14,14.29,14.29,14.29],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Oparin R. D. et al. Impregnation of Polymethyl Methacrylate with Carbamazepine in Supercritical Carbon Dioxide // Russian Journal of Physical Chemistry B. 2021. Vol. 15. No. 7. pp. 1157-1165.
GOST all authors (up to 50)
Copy
Oparin R. D., Belov K. V., Khodov I. A., Dyshin A. A., Kiselev M. G. Impregnation of Polymethyl Methacrylate with Carbamazepine in Supercritical Carbon Dioxide // Russian Journal of Physical Chemistry B. 2021. Vol. 15. No. 7. pp. 1157-1165.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S1990793121070101
UR - https://doi.org/10.1134%2FS1990793121070101
TI - Impregnation of Polymethyl Methacrylate with Carbamazepine in Supercritical Carbon Dioxide
T2 - Russian Journal of Physical Chemistry B
AU - Oparin, R D
AU - Belov, K. V.
AU - Khodov, I A
AU - Dyshin, A A
AU - Kiselev, M G
PY - 2021
DA - 2021/12/01 00:00:00
PB - Pleiades Publishing
SP - 1157-1165
IS - 7
VL - 15
SN - 1990-7931
SN - 1990-7923
ER -
Cite this
BibTex
Copy
@article{2021_Oparin
author = {R D Oparin and K. V. Belov and I A Khodov and A A Dyshin and M G Kiselev},
title = {Impregnation of Polymethyl Methacrylate with Carbamazepine in Supercritical Carbon Dioxide},
journal = {Russian Journal of Physical Chemistry B},
year = {2021},
volume = {15},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134%2FS1990793121070101},
number = {7},
pages = {1157--1165},
doi = {10.1134/S1990793121070101}
}
Cite this
MLA
Copy
Oparin, R. D., et al. “Impregnation of Polymethyl Methacrylate with Carbamazepine in Supercritical Carbon Dioxide.” Russian Journal of Physical Chemistry B, vol. 15, no. 7, Dec. 2021, pp. 1157-1165. https://doi.org/10.1134%2FS1990793121070101.
Labs