volume 6 issue 5-6 pages 323-329

Bimetallic Pd-M (M = Co, Ni, Zn, Ag) nanoparticles containing transition metals: Synthesis, characterization, and catalytic performance

Publication typeJournal Article
Publication date2011-06-17
SJR
CiteScore
Impact factor
ISSN19950780, 19950799
Condensed Matter Physics
General Materials Science
General Engineering
Abstract
The reductive thermolysis of Pd(OOCMe)4M(OH2) (M = NiII, CoII, ZnII) and Pd(OOCMe)4Ag2(HOOCMe)4 molecular complexes results in the generation of bimetallic Pd-based Pd-M (M = Co, Ni, Zn, Ag) nanoparticles. The composition and morphology of nanoparticles and the electron state of metal atoms were characterized using electron microscopy, elemental ICP analysis, X-ray diffraction, and XAFS (XANES/EXAFS) techniques. The catalytic performance of nanoparticles was studied using the example of reactions of catalytic hydrazine decomposition and U(VI) reduction to U(IV) by hydrazine and formic acid. The catalytic performance of Pd-Ni nanoparticles is superior to that of the standard supported Pd/SiO2 catalyst containing a similar amount of Pd atoms, while Pd-Co, Pd-Zn, and Pd-Ag nanoparticles do not catalyze the studied reactions.
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Ershov B. G. et al. Bimetallic Pd-M (M = Co, Ni, Zn, Ag) nanoparticles containing transition metals: Synthesis, characterization, and catalytic performance // Nanotechnologies in Russia. 2011. Vol. 6. No. 5-6. pp. 323-329.
GOST all authors (up to 50) Copy
Ershov B. G., Ananev A. V., Abkhalimov E. V., Kochubei D., Kriventsov V., Plyasova L. M., Molina I. Y., Kozitsyna N., Nefedov S., Vargaftik M., Moiseev I. I. Bimetallic Pd-M (M = Co, Ni, Zn, Ag) nanoparticles containing transition metals: Synthesis, characterization, and catalytic performance // Nanotechnologies in Russia. 2011. Vol. 6. No. 5-6. pp. 323-329.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S1995078011030050
UR - http://link.springer.com/10.1134/S1995078011030050
TI - Bimetallic Pd-M (M = Co, Ni, Zn, Ag) nanoparticles containing transition metals: Synthesis, characterization, and catalytic performance
T2 - Nanotechnologies in Russia
AU - Ershov, B G
AU - Ananev, A V
AU - Abkhalimov, E V
AU - Kochubei, D.I.
AU - Kriventsov, V.V.
AU - Plyasova, L. M.
AU - Molina, I. Yu.
AU - Kozitsyna, N.Yu.
AU - Nefedov, S.E.
AU - Vargaftik, M.N.
AU - Moiseev, I. I.
PY - 2011
DA - 2011/06/17
PB - Pleiades Publishing
SP - 323-329
IS - 5-6
VL - 6
SN - 1995-0780
SN - 1995-0799
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2011_Ershov,
author = {B G Ershov and A V Ananev and E V Abkhalimov and D.I. Kochubei and V.V. Kriventsov and L. M. Plyasova and I. Yu. Molina and N.Yu. Kozitsyna and S.E. Nefedov and M.N. Vargaftik and I. I. Moiseev},
title = {Bimetallic Pd-M (M = Co, Ni, Zn, Ag) nanoparticles containing transition metals: Synthesis, characterization, and catalytic performance},
journal = {Nanotechnologies in Russia},
year = {2011},
volume = {6},
publisher = {Pleiades Publishing},
month = {jun},
url = {http://link.springer.com/10.1134/S1995078011030050},
number = {5-6},
pages = {323--329},
doi = {10.1134/S1995078011030050}
}
MLA
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MLA Copy
Ershov, B. G., et al. “Bimetallic Pd-M (M = Co, Ni, Zn, Ag) nanoparticles containing transition metals: Synthesis, characterization, and catalytic performance.” Nanotechnologies in Russia, vol. 6, no. 5-6, Jun. 2011, pp. 323-329. http://link.springer.com/10.1134/S1995078011030050.