Membranes and Membrane Technologies, volume 4, issue 3, pages 189-194
Mobility of Li+, Na+, Cs+ Cations in Sulfocation-Exchange Membranes Based on Polyethylene and Grafted Sulfonated Polystyrene Studied by NMR Relaxation
V. I. Volkov
1, 2
,
N. A. Slesarenko
1
,
A V Chernyak
1, 2
,
V A Zabrodin
1
,
D V Golubenko
3
,
V.A. Tverskoy
4
,
2
Scientific Center in Chernogolovka, Russian Academy of Sciences, Chernogolovka, Russia
|
3
Publication type: Journal Article
Publication date: 2022-06-07
Journal:
Membranes and Membrane Technologies
Quartile SCImago
Q3
Quartile WOS
—
Impact factor: 1.1
ISSN: 25177516, 25177524
General Environmental Science
General Earth and Planetary Sciences
Abstract
Mobility of alkaline metal cations Li+, Na+, Cs+ in membranes based on polyethylene and sulfonated grafted polystyrene has been investigated by NMR relaxation technique. The kinetic curves of longitude recovery and transverse decay magnetizations of 7Li, 23Na, 133Cs nuclei were recorded. It was indicated that spin relaxation is due to interaction of nuclear quadrupole moment with electric field gradient generated by cation hydrated water molecules and sulfonate groups. The correlation times and activation energies of translational cation mobility have been calculated from spin-lattice (T1) and spin-spin (Т2) relaxation temperature dependences. Cation mobility increases in the next sequence Li+ < Na+ < Cs+. Diffusion coefficients calculated from NMR relaxation have been compared with macroscopic diffusion coefficients measured by pulsed field gradient NMR and impedance spectroscopy techniques. On the basis of this comparison, a model of heterogeneous membrane ionic transfer is discussed. It has been shown that membrane conductivity is restricted by ionic transfer in narrow pores with low functional group concentration.
Top-30
Citations by journals
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2
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Membranes and Membrane Technologies
2 publications, 28.57%
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Mendeleev Communications
1 publication, 14.29%
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Journal of Materials Chemistry A
1 publication, 14.29%
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Membranes
1 publication, 14.29%
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Russian Chemical Reviews
1 publication, 14.29%
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2
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Citations by publishers
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2
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Pleiades Publishing
2 publications, 28.57%
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Elsevier
1 publication, 14.29%
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Royal Society of Chemistry (RSC)
1 publication, 14.29%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 14.29%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 14.29%
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2
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Volkov V. I. et al. Mobility of Li+, Na+, Cs+ Cations in Sulfocation-Exchange Membranes Based on Polyethylene and Grafted Sulfonated Polystyrene Studied by NMR Relaxation // Membranes and Membrane Technologies. 2022. Vol. 4. No. 3. pp. 189-194.
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Volkov V. I., Slesarenko N. A., Chernyak A. V., Zabrodin V. A., Golubenko D. V., Tverskoy V., Yaroslavtsev A. B. Mobility of Li+, Na+, Cs+ Cations in Sulfocation-Exchange Membranes Based on Polyethylene and Grafted Sulfonated Polystyrene Studied by NMR Relaxation // Membranes and Membrane Technologies. 2022. Vol. 4. No. 3. pp. 189-194.
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TY - JOUR
DO - 10.1134/S2517751622030076
UR - https://link.springer.com/10.1134/S2517751622030076
TI - Mobility of Li+, Na+, Cs+ Cations in Sulfocation-Exchange Membranes Based on Polyethylene and Grafted Sulfonated Polystyrene Studied by NMR Relaxation
T2 - Membranes and Membrane Technologies
AU - Volkov, V. I.
AU - Chernyak, A V
AU - Zabrodin, V A
AU - Golubenko, D V
AU - Yaroslavtsev, A. B.
AU - Slesarenko, N. A.
AU - Tverskoy, V.A.
PY - 2022
DA - 2022/06/07 00:00:00
PB - Pleiades Publishing
SP - 189-194
IS - 3
VL - 4
SN - 2517-7516
SN - 2517-7524
ER -
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@article{2022_Volkov,
author = {V. I. Volkov and A V Chernyak and V A Zabrodin and D V Golubenko and A. B. Yaroslavtsev and N. A. Slesarenko and V.A. Tverskoy},
title = {Mobility of Li+, Na+, Cs+ Cations in Sulfocation-Exchange Membranes Based on Polyethylene and Grafted Sulfonated Polystyrene Studied by NMR Relaxation},
journal = {Membranes and Membrane Technologies},
year = {2022},
volume = {4},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://link.springer.com/10.1134/S2517751622030076},
number = {3},
pages = {189--194},
doi = {10.1134/S2517751622030076}
}
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Volkov, V. I., et al. “Mobility of Li+, Na+, Cs+ Cations in Sulfocation-Exchange Membranes Based on Polyethylene and Grafted Sulfonated Polystyrene Studied by NMR Relaxation.” Membranes and Membrane Technologies, vol. 4, no. 3, Jun. 2022, pp. 189-194. https://link.springer.com/10.1134/S2517751622030076.