Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media
Publication type: Journal Article
Publication date: 2021-10-01
scimago Q3
wos Q4
SJR: 0.205
CiteScore: 1.3
Impact factor: 1.0
ISSN: 00125008, 16083113
General Chemistry
Abstract
For the first time the reactions of radical nitration of alkenes and oxiranes with nitrogen dioxide in the liquid and supercritical carbon dioxide (sc-CO2) media were carried out. Using octene-1, styrene, and their derivatives as examples, the effectiveness of the developed method for obtaining valuable 1,2-functionalized products, including nitroalcohols, dinitroalkanes, and nitronitrates have been shown. Due to the application of sc-CO2, the proposed method compares favorably with known analogs by the absence of by-products and waste organic solvents, as well as lesser fire and explosion hazards.
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Ivanov R. E., Zharkov M. N., Zlotin S. G. Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media // Doklady Chemistry. 2021. Vol. 500. No. 2. pp. 209-212.
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Ivanov R. E., Zharkov M. N., Zlotin S. G. Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media // Doklady Chemistry. 2021. Vol. 500. No. 2. pp. 209-212.
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RIS
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TY - JOUR
DO - 10.1134/s0012500821100037
UR - https://doi.org/10.1134/s0012500821100037
TI - Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media
T2 - Doklady Chemistry
AU - Ivanov, R E
AU - Zharkov, M N
AU - Zlotin, S. G.
PY - 2021
DA - 2021/10/01
PB - Pleiades Publishing
SP - 209-212
IS - 2
VL - 500
SN - 0012-5008
SN - 1608-3113
ER -
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BibTex (up to 50 authors)
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@article{2021_Ivanov,
author = {R E Ivanov and M N Zharkov and S. G. Zlotin},
title = {Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media},
journal = {Doklady Chemistry},
year = {2021},
volume = {500},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/s0012500821100037},
number = {2},
pages = {209--212},
doi = {10.1134/s0012500821100037}
}
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MLA
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Ivanov, R. E., et al. “Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media.” Doklady Chemistry, vol. 500, no. 2, Oct. 2021, pp. 209-212. https://doi.org/10.1134/s0012500821100037.
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