volume 51 issue 6 pages 409-414

Two-quantum photochemistry of the complex cis,trans-[PtIV(en)(I)2(CH3COO)2]

Publication typeJournal Article
Publication date2017-11-23
scimago Q4
wos Q4
SJR0.178
CiteScore0.9
Impact factor0.6
ISSN00181439, 16083148
Physical and Theoretical Chemistry
Abstract
The two-quantum photochemistry of aqueous solutions of cis,trans-[PtIV(en)(I)2(CH3COO)2] (complex 1) has been studied by laser flash photolysis using an irradiation wavelength of 355 nm. This compound can be considered as a model representative of the mixed-ligand Pt(IV) complexes tested for use in photodynamic therapy. The appearance of transient absorption, presumably due to two consecutively produced Pt(III) complexes, has been revealed. The spectral and kinetic characteristics of the intermediates have been determined. A mechanism of two-quantum photolysis of complex 1 is proposed on the basis of the data obtained.
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Glebov E. et al. Two-quantum photochemistry of the complex cis,trans-[PtIV(en)(I)2(CH3COO)2] // High Energy Chemistry. 2017. Vol. 51. No. 6. pp. 409-414.
GOST all authors (up to 50) Copy
Glebov E., Grivin V. P., Vasilchenko D. B., Zadesenets A. V., Plyusnin V. F. Two-quantum photochemistry of the complex cis,trans-[PtIV(en)(I)2(CH3COO)2] // High Energy Chemistry. 2017. Vol. 51. No. 6. pp. 409-414.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/s0018143917060078
UR - https://doi.org/10.1134/s0018143917060078
TI - Two-quantum photochemistry of the complex cis,trans-[PtIV(en)(I)2(CH3COO)2]
T2 - High Energy Chemistry
AU - Glebov, E.M
AU - Grivin, V P
AU - Vasilchenko, D B
AU - Zadesenets, A V
AU - Plyusnin, V F
PY - 2017
DA - 2017/11/23
PB - Pleiades Publishing
SP - 409-414
IS - 6
VL - 51
SN - 0018-1439
SN - 1608-3148
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2017_Glebov,
author = {E.M Glebov and V P Grivin and D B Vasilchenko and A V Zadesenets and V F Plyusnin},
title = {Two-quantum photochemistry of the complex cis,trans-[PtIV(en)(I)2(CH3COO)2]},
journal = {High Energy Chemistry},
year = {2017},
volume = {51},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/s0018143917060078},
number = {6},
pages = {409--414},
doi = {10.1134/s0018143917060078}
}
MLA
Cite this
MLA Copy
Glebov, E.M, et al. “Two-quantum photochemistry of the complex cis,trans-[PtIV(en)(I)2(CH3COO)2].” High Energy Chemistry, vol. 51, no. 6, Nov. 2017, pp. 409-414. https://doi.org/10.1134/s0018143917060078.