On the Cause of Solvent Effect in $${\text{Pt}^{\text{IV}}}\text{Cl}_{6}^{{2 - }}$$ Photochemistry
Publication type: Journal Article
Publication date: 2021-05-01
scimago Q4
wos Q4
SJR: 0.178
CiteScore: 0.9
Impact factor: 0.6
ISSN: 00181439, 16083148
Physical and Theoretical Chemistry
Abstract
The photochemistry of hexachloroplatinate(IV) paradoxically depends on the solvent. Chain photosolvation of the complex occurs in water, chloroform, and acetonitrile, with the photolysis mechanism being quite identical in water and chloroform, whereas the formation of a chain carrier in acetonitrile has a peculiar feature. In alcohols, the photochemical reaction is not a chain process, being a combination of photosolvation and photoreduction of Pt(IV) to Pt(II). It has been shown that the principal factors accounting for the solvent effect are the values of the rate constants of key reactions.
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Glebov E. M., Plyusnin V. F. On the Cause of Solvent Effect in $${\text{Pt}^{\text{IV}}}\text{Cl}_{6}^{{2 - }}$$ Photochemistry // High Energy Chemistry. 2021. Vol. 55. No. 3. pp. 203-211.
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Glebov E. M., Plyusnin V. F. On the Cause of Solvent Effect in $${\text{Pt}^{\text{IV}}}\text{Cl}_{6}^{{2 - }}$$ Photochemistry // High Energy Chemistry. 2021. Vol. 55. No. 3. pp. 203-211.
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TY - JOUR
DO - 10.1134/s0018143921030036
UR - https://doi.org/10.1134/s0018143921030036
TI - On the Cause of Solvent Effect in $${\text{Pt}^{\text{IV}}}\text{Cl}_{6}^{{2 - }}$$ Photochemistry
T2 - High Energy Chemistry
AU - Glebov, E M
AU - Plyusnin, V F
PY - 2021
DA - 2021/05/01
PB - Pleiades Publishing
SP - 203-211
IS - 3
VL - 55
SN - 0018-1439
SN - 1608-3148
ER -
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BibTex (up to 50 authors)
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@article{2021_Glebov,
author = {E M Glebov and V F Plyusnin},
title = {On the Cause of Solvent Effect in $${\text{Pt}^{\text{IV}}}\text{Cl}_{6}^{{2 - }}$$ Photochemistry},
journal = {High Energy Chemistry},
year = {2021},
volume = {55},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134/s0018143921030036},
number = {3},
pages = {203--211},
doi = {10.1134/s0018143921030036}
}
Cite this
MLA
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Glebov, E. M., and V F Plyusnin. “On the Cause of Solvent Effect in $${\text{Pt}^{\text{IV}}}\text{Cl}_{6}^{{2 - }}$$ Photochemistry.” High Energy Chemistry, vol. 55, no. 3, May. 2021, pp. 203-211. https://doi.org/10.1134/s0018143921030036.