On the initial stage of the free-radical polymerizations of styrene and methyl methacrylate in the presence of fullerene C60
Publication type: Journal Article
Publication date: 2016-05-01
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
It has been demonstrated experimentally and theoretically that the essentially different inhibiting effects of fullerene C60 on the initial stage of the polymerizations of styrene and methyl methacrylate (including complete hampering of styrene polymerization throughout a long induction period) are of common kinetic nature. The difference arises from the competition between C60 and the monomer not for initiating radicals but for radicals originating from the monomer; that is, the difference stems from the competition between the chain propagation reactions and the termination reactions on fullerene molecules. As a consequence, the further development of the process is determined by the relative reactivities of the radicals toward C60 and towards their parent monomers.
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11
Total citations:
11
Citations from 2025:
2
(18.18%)
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GOST
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Yumagulova R. et al. On the initial stage of the free-radical polymerizations of styrene and methyl methacrylate in the presence of fullerene C60 // Kinetics and Catalysis. 2016. Vol. 57. No. 3. pp. 380-387.
GOST all authors (up to 50)
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Yumagulova R., Kuznetsov S. I., Diniakhmetova D. R., Frizen A. K., Kraikin V. A., Kolesov S. V. On the initial stage of the free-radical polymerizations of styrene and methyl methacrylate in the presence of fullerene C60 // Kinetics and Catalysis. 2016. Vol. 57. No. 3. pp. 380-387.
Cite this
RIS
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TY - JOUR
DO - 10.1134/s0023158416030150
UR - https://doi.org/10.1134/s0023158416030150
TI - On the initial stage of the free-radical polymerizations of styrene and methyl methacrylate in the presence of fullerene C60
T2 - Kinetics and Catalysis
AU - Yumagulova, R.Kh.
AU - Kuznetsov, S. I.
AU - Diniakhmetova, D R
AU - Frizen, A K
AU - Kraikin, V A
AU - Kolesov, S. V.
PY - 2016
DA - 2016/05/01
PB - Pleiades Publishing
SP - 380-387
IS - 3
VL - 57
SN - 0023-1584
SN - 1608-3210
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Yumagulova,
author = {R.Kh. Yumagulova and S. I. Kuznetsov and D R Diniakhmetova and A K Frizen and V A Kraikin and S. V. Kolesov},
title = {On the initial stage of the free-radical polymerizations of styrene and methyl methacrylate in the presence of fullerene C60},
journal = {Kinetics and Catalysis},
year = {2016},
volume = {57},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134/s0023158416030150},
number = {3},
pages = {380--387},
doi = {10.1134/s0023158416030150}
}
Cite this
MLA
Copy
Yumagulova, R.Kh., et al. “On the initial stage of the free-radical polymerizations of styrene and methyl methacrylate in the presence of fullerene C60.” Kinetics and Catalysis, vol. 57, no. 3, May. 2016, pp. 380-387. https://doi.org/10.1134/s0023158416030150.