volume 64 issue 5 pages 683-685

Relationship between the Activity of Oxide Catalysts in the Reaction of Ozone Decomposition and O3-Catalytic Oxidation of n-С4H10

Publication typeJournal Article
Publication date2023-10-05
scimago Q3
wos Q4
SJR0.260
CiteScore1.9
Impact factor1.4
ISSN00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The activity of transition metal (V, Cr, Mn, Fe, Co, Ni, Cu, and Zn) oxides supported on γ-Al2O3 in the reaction of ozone decomposition was studied. The catalytic characteristics of the samples with high (NiO/Al2O3), low (Cr2O3/Al2O3), and intermediate (MnOx/Al2O3) activity in ozone decomposition were studied in the process of ozone catalytic oxidation (OZCO) of n-butane. The results obtained allowed us to conclude that the optimal activity of a transition metal oxide in the decomposition of O3 is of key importance in the OZCO process. At a low rate of ozone decomposition, hydrocarbon oxidation is limited by the rate of formation of atomic oxygen species; at an excessively high rate of decomposition, hydrocarbon conversion decreases due to an competitive process of atomic oxygen recombination. The best catalytic performance in the oxidation of n-C4H10 was observed for a catalyst based on Mn oxide, which has an optimal activity in the decomposition of O3.
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Bokarev D. A. et al. Relationship between the Activity of Oxide Catalysts in the Reaction of Ozone Decomposition and O3-Catalytic Oxidation of n-С4H10 // Kinetics and Catalysis. 2023. Vol. 64. No. 5. pp. 683-685.
GOST all authors (up to 50) Copy
Bokarev D. A., Paramoshin I. V., Kanaev S. A., Stakheev A. Relationship between the Activity of Oxide Catalysts in the Reaction of Ozone Decomposition and O3-Catalytic Oxidation of n-С4H10 // Kinetics and Catalysis. 2023. Vol. 64. No. 5. pp. 683-685.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/s0023158423050026
UR - https://doi.org/10.1134/s0023158423050026
TI - Relationship between the Activity of Oxide Catalysts in the Reaction of Ozone Decomposition and O3-Catalytic Oxidation of n-С4H10
T2 - Kinetics and Catalysis
AU - Bokarev, D A
AU - Paramoshin, I. V.
AU - Kanaev, S A
AU - Stakheev, A.Yu
PY - 2023
DA - 2023/10/05
PB - Pleiades Publishing
SP - 683-685
IS - 5
VL - 64
SN - 0023-1584
SN - 1608-3210
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Bokarev,
author = {D A Bokarev and I. V. Paramoshin and S A Kanaev and A.Yu Stakheev},
title = {Relationship between the Activity of Oxide Catalysts in the Reaction of Ozone Decomposition and O3-Catalytic Oxidation of n-С4H10},
journal = {Kinetics and Catalysis},
year = {2023},
volume = {64},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/s0023158423050026},
number = {5},
pages = {683--685},
doi = {10.1134/s0023158423050026}
}
MLA
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MLA Copy
Bokarev, D. A., et al. “Relationship between the Activity of Oxide Catalysts in the Reaction of Ozone Decomposition and O3-Catalytic Oxidation of n-С4H10.” Kinetics and Catalysis, vol. 64, no. 5, Oct. 2023, pp. 683-685. https://doi.org/10.1134/s0023158423050026.