Support Effect on the Characteristics of Supported Manganese Catalysts in the O3-Catalytic Oxidation of Volatile Organic Compounds
Publication type: Journal Article
Publication date: 2023-12-12
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The characteristics of Mn catalysts supported on different carriers (SiO2 and BEA zeolite) in the processes of ozone decomposition and ozone-catalytic oxidation (OZCO) of volatile organic compounds (VOCs) were studied using n-butane as an example. The parent SiO2 was inactive in the test reactions, and the characteristics of Mn/SiO2 were determined by the catalytic properties of the supported MnOx oxide. In contrast to SiO2, BEA zeolite demonstrated significant catalytic activity, although at a temperature 50°C higher than that for Mn/BEA. The data obtained allowed us to conclude that the catalytic characteristics of Mn/BEA at 30–100°C were also determined by the Mn component of the catalyst. At higher temperatures, the catalytic properties of BEA significantly affected the course of the OZCO process. The zeolite carrier improved hydrocarbon conversion at 100–200°C and decreased the amount of ozone required for the OZCO process over Mn/BEA.
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Bokarev D. A. et al. Support Effect on the Characteristics of Supported Manganese Catalysts in the O3-Catalytic Oxidation of Volatile Organic Compounds // Kinetics and Catalysis. 2023. Vol. 64. No. 6. pp. 862-871.
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Bokarev D. A., Paramoshin I. V., Rassolov A. V., Kanaev S. A., Bragina G. O., Stakheev A. Support Effect on the Characteristics of Supported Manganese Catalysts in the O3-Catalytic Oxidation of Volatile Organic Compounds // Kinetics and Catalysis. 2023. Vol. 64. No. 6. pp. 862-871.
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TY - JOUR
DO - 10.1134/s0023158423060034
UR - https://doi.org/10.1134/s0023158423060034
TI - Support Effect on the Characteristics of Supported Manganese Catalysts in the O3-Catalytic Oxidation of Volatile Organic Compounds
T2 - Kinetics and Catalysis
AU - Bokarev, D A
AU - Paramoshin, I. V.
AU - Rassolov, A V
AU - Kanaev, S A
AU - Bragina, G O
AU - Stakheev, A.Yu
PY - 2023
DA - 2023/12/12
PB - Pleiades Publishing
SP - 862-871
IS - 6
VL - 64
SN - 0023-1584
SN - 1608-3210
ER -
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@article{2023_Bokarev,
author = {D A Bokarev and I. V. Paramoshin and A V Rassolov and S A Kanaev and G O Bragina and A.Yu Stakheev},
title = {Support Effect on the Characteristics of Supported Manganese Catalysts in the O3-Catalytic Oxidation of Volatile Organic Compounds},
journal = {Kinetics and Catalysis},
year = {2023},
volume = {64},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/s0023158423060034},
number = {6},
pages = {862--871},
doi = {10.1134/s0023158423060034}
}
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MLA
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Bokarev, D. A., et al. “Support Effect on the Characteristics of Supported Manganese Catalysts in the O3-Catalytic Oxidation of Volatile Organic Compounds.” Kinetics and Catalysis, vol. 64, no. 6, Dec. 2023, pp. 862-871. https://doi.org/10.1134/s0023158423060034.