EPR Spectroscopy of Mn2+ Cations in Chalcopyrite CuGaSe2 Matrix
Publication type: Journal Article
Publication date: 2021-01-01
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Manganese-doped semiconductors CuGa1 – xMnxSe2 (x = 0.02–0.20) with a chalcopyrite structure have been studied by EPR spectroscopy. For all samples, a singlet signal with g factor equal to ~2.00 is observed, the width of which decreases with an increase in the manganese concentration from 22.5 to 16.2 mT. For the most diluted sample with x = 0.02, a fine and hyperfine structure of the spectrum of the Mn2+ ion is observed in the high-frequency W-range (93 GHz). The hyperfine splitting parameter A has been estimated and the longitudinal and transverse relaxation times at 10 K have been determined by the electron spin echo method.
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Russian Journal of Inorganic Chemistry
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Zykin M. A. et al. EPR Spectroscopy of Mn2+ Cations in Chalcopyrite CuGaSe2 Matrix // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 1. pp. 113-116.
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Zykin M. A., Aminov T. G., Minin V. V., Efimov N. N. EPR Spectroscopy of Mn2+ Cations in Chalcopyrite CuGaSe2 Matrix // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 1. pp. 113-116.
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TY - JOUR
DO - 10.1134/s0036023621010137
UR - https://doi.org/10.1134/s0036023621010137
TI - EPR Spectroscopy of Mn2+ Cations in Chalcopyrite CuGaSe2 Matrix
T2 - Russian Journal of Inorganic Chemistry
AU - Zykin, M. A.
AU - Aminov, T. G.
AU - Minin, V V
AU - Efimov, N. N.
PY - 2021
DA - 2021/01/01
PB - Pleiades Publishing
SP - 113-116
IS - 1
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2021_Zykin,
author = {M. A. Zykin and T. G. Aminov and V V Minin and N. N. Efimov},
title = {EPR Spectroscopy of Mn2+ Cations in Chalcopyrite CuGaSe2 Matrix},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1134/s0036023621010137},
number = {1},
pages = {113--116},
doi = {10.1134/s0036023621010137}
}
Cite this
MLA
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Zykin, M. A., et al. “EPR Spectroscopy of Mn2+ Cations in Chalcopyrite CuGaSe2 Matrix.” Russian Journal of Inorganic Chemistry, vol. 66, no. 1, Jan. 2021, pp. 113-116. https://doi.org/10.1134/s0036023621010137.
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