Russian Journal of Inorganic Chemistry, volume 67, issue 2, pages 150-157

Synthesis and Magnetic Properties of CuGaSe2:Mn Manganese-Doped Chalcopyrites

Publication type: Journal Article
Publication date: 2022-02-01
scimago Q3
SJR: 0.316
CiteScore: 3.1
Impact factor: 1.8
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Two series of manganese-doped chalcopyrites Cu1 – x/2Ga1 – x/2MnxSe2 and CuGa1 – xMnxSe2 have been prepared by solid-phase synthesis. Manganese-containing impurities have been found in all samples because of low solubility of manganese in chalcopyrite CuGaSe2. Nevertheless, manganese is incorporated into the chalcopyrite structure in a noticeable amount. All manganese-containing chalcopyrites have mainly paramagnetic properties; however, a ferromagnetic contribution has been found for all samples.
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