Heterocene Catalysts for Copolymerization of Hex-1-ene and Polar Vinyl Monomers
G. I. Sadrtdinova
1, 2
,
Valeriya Ovchinnikova
1, 3
,
Pavel D. Komarov
1
,
Sergey O. Ilyin
1
,
Alexey A. Vinogradov
1
,
Pavel V Ivchenko
1, 3
,
Ilya E. Nifant'ev
1, 2, 3
Publication type: Journal Article
Publication date: 2024-12-02
scimago Q3
wos Q3
SJR: 0.272
CiteScore: 2.2
Impact factor: 1.1
ISSN: 09655441, 15556239
Abstract
The paper proposes a series of promising Zr(IV) complexes and experimentally confirms that, when activated with minimal amounts of modified metylaluminoxane MMAO-12 ([Al]/[Zr] ~20–40), these complexes are able to initiate copolymerization of hex-1-ene with polar vinyl monomers FG-(CH2)8CH=CH2 [where FG is a functional group selected from C(O)NMe2, CH2OSiMe3, C(O)OiPr, and CH2OH]. The prepared copolymers were characterized by 1H and 13C NMR spectroscopy, size exclusion chromatography, and differential scanning calorimetry. Isotactic copolymers of hex-1-ene with 10-undecen-1-ol with polar comonomer content up to 32.2 mol % have been synthesized for the first time. An investigation of the adhesive properties of the prepared copolymers has shown that incorporating 10-undecen-1-ol enhances the adhesive fracture energy by a factor of 32 compared to the respective homopolymer.
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Citations from 2024:
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(100%)
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Sadrtdinova G. I. et al. Heterocene Catalysts for Copolymerization of Hex-1-ene and Polar Vinyl Monomers // Petroleum Chemistry. 2024. Vol. 64. No. 11. pp. 1253-1265.
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Sadrtdinova G. I., Ovchinnikova V., Komarov P. D., Ilyin S. O., Vinogradov A. A., Vinogradov A. A., Ivchenko P. V., Nifant'ev I. E. Heterocene Catalysts for Copolymerization of Hex-1-ene and Polar Vinyl Monomers // Petroleum Chemistry. 2024. Vol. 64. No. 11. pp. 1253-1265.
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TY - JOUR
DO - 10.1134/s0965544124060161
UR - https://link.springer.com/10.1134/S0965544124060161
TI - Heterocene Catalysts for Copolymerization of Hex-1-ene and Polar Vinyl Monomers
T2 - Petroleum Chemistry
AU - Sadrtdinova, G. I.
AU - Ovchinnikova, Valeriya
AU - Komarov, Pavel D.
AU - Ilyin, Sergey O.
AU - Vinogradov, Alexander A
AU - Vinogradov, Alexey A.
AU - Ivchenko, Pavel V
AU - Nifant'ev, Ilya E.
PY - 2024
DA - 2024/12/02
PB - Pleiades Publishing
SP - 1253-1265
IS - 11
VL - 64
SN - 0965-5441
SN - 1555-6239
ER -
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@article{2024_Sadrtdinova,
author = {G. I. Sadrtdinova and Valeriya Ovchinnikova and Pavel D. Komarov and Sergey O. Ilyin and Alexander A Vinogradov and Alexey A. Vinogradov and Pavel V Ivchenko and Ilya E. Nifant'ev},
title = {Heterocene Catalysts for Copolymerization of Hex-1-ene and Polar Vinyl Monomers},
journal = {Petroleum Chemistry},
year = {2024},
volume = {64},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://link.springer.com/10.1134/S0965544124060161},
number = {11},
pages = {1253--1265},
doi = {10.1134/s0965544124060161}
}
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MLA
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Sadrtdinova, G. I., et al. “Heterocene Catalysts for Copolymerization of Hex-1-ene and Polar Vinyl Monomers.” Petroleum Chemistry, vol. 64, no. 11, Dec. 2024, pp. 1253-1265. https://link.springer.com/10.1134/S0965544124060161.