Gas-phase basicity: Parameter determining the efficiency of laser desorption/ionization from silicon surfaces
Publication type: Journal Article
Publication date: 2012-12-29
scimago Q3
wos Q4
SJR: 0.252
CiteScore: 1.9
Impact factor: 1.1
ISSN: 10619348, 16083199
Analytical Chemistry
Abstract
The efficiency of laser desorption/ionization of twenty compounds from the surface of amorphous silicon is studied as a function of proton affinity (PA) and gas-phase basicity (GB). The values of GB and PA are obtained from quantum-chemical calculations using the density functional theory in the B3LYP model with the 6–311++G(3df,3pd) basis set. The values of GB lie in the range from 845 to 977 kJ/mol. The efficiency of laser desorption/ionization exponentially depends on the GB and PA values and for the studied compounds varies from 7 × 10−6 to 1.4 × 10−2.
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Alimpiev S. S., Nikiforov S. M., Simanovsky Ya. O. Gas-phase basicity: Parameter determining the efficiency of laser desorption/ionization from silicon surfaces // Journal of Analytical Chemistry. 2012. Vol. 68. No. 1. pp. 19-26.
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Alimpiev S. S., Nikiforov S. M., Simanovsky Ya. O. Gas-phase basicity: Parameter determining the efficiency of laser desorption/ionization from silicon surfaces // Journal of Analytical Chemistry. 2012. Vol. 68. No. 1. pp. 19-26.
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RIS
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TY - JOUR
DO - 10.1134/s1061934812110056
UR - https://doi.org/10.1134/s1061934812110056
TI - Gas-phase basicity: Parameter determining the efficiency of laser desorption/ionization from silicon surfaces
T2 - Journal of Analytical Chemistry
AU - Alimpiev, S S
AU - Nikiforov, S M
AU - Simanovsky, Ya O
PY - 2012
DA - 2012/12/29
PB - Pleiades Publishing
SP - 19-26
IS - 1
VL - 68
SN - 1061-9348
SN - 1608-3199
ER -
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BibTex (up to 50 authors)
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@article{2012_Alimpiev,
author = {S S Alimpiev and S M Nikiforov and Ya O Simanovsky},
title = {Gas-phase basicity: Parameter determining the efficiency of laser desorption/ionization from silicon surfaces},
journal = {Journal of Analytical Chemistry},
year = {2012},
volume = {68},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/s1061934812110056},
number = {1},
pages = {19--26},
doi = {10.1134/s1061934812110056}
}
Cite this
MLA
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Alimpiev, S. S., et al. “Gas-phase basicity: Parameter determining the efficiency of laser desorption/ionization from silicon surfaces.” Journal of Analytical Chemistry, vol. 68, no. 1, Dec. 2012, pp. 19-26. https://doi.org/10.1134/s1061934812110056.