Kinetics and mechanism of triphenylphosphine quarternization with unsaturated carboxylic acids in the medium of acetic acid
Publication type: Journal Article
Publication date: 2009-05-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
Kinetics of reaction of triphenylphosphine with a series of unsaturated carboxylic acids and related esters in the medium of acetic acid as well as in mixtures of acetic acid and acetonitrile was studied by spectrophotometry. The data obtained show that the process of quarternization should be described by kinetic equation of third order, the proton transfer occurs from the solvent. A stepwise mechanism of interaction including formation of prereaction complex on the reaction pathway is proposed.
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GOST
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Galkin V. I. et al. Kinetics and mechanism of triphenylphosphine quarternization with unsaturated carboxylic acids in the medium of acetic acid // Russian Journal of General Chemistry. 2009. Vol. 79. No. 5. pp. 919-924.
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Galkin V. I., Salin A. V., Bakhtiyarova Yu. V., Sobanov A. A. Kinetics and mechanism of triphenylphosphine quarternization with unsaturated carboxylic acids in the medium of acetic acid // Russian Journal of General Chemistry. 2009. Vol. 79. No. 5. pp. 919-924.
Cite this
RIS
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TY - JOUR
DO - 10.1134/s1070363209050090
UR - https://doi.org/10.1134/s1070363209050090
TI - Kinetics and mechanism of triphenylphosphine quarternization with unsaturated carboxylic acids in the medium of acetic acid
T2 - Russian Journal of General Chemistry
AU - Galkin, V. I.
AU - Salin, A V
AU - Bakhtiyarova, Yu V
AU - Sobanov, A A
PY - 2009
DA - 2009/05/01
PB - Pleiades Publishing
SP - 919-924
IS - 5
VL - 79
SN - 1070-3632
SN - 1608-3350
ER -
Cite this
BibTex (up to 50 authors)
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@article{2009_Galkin,
author = {V. I. Galkin and A V Salin and Yu V Bakhtiyarova and A A Sobanov},
title = {Kinetics and mechanism of triphenylphosphine quarternization with unsaturated carboxylic acids in the medium of acetic acid},
journal = {Russian Journal of General Chemistry},
year = {2009},
volume = {79},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134/s1070363209050090},
number = {5},
pages = {919--924},
doi = {10.1134/s1070363209050090}
}
Cite this
MLA
Copy
Galkin, V. I., et al. “Kinetics and mechanism of triphenylphosphine quarternization with unsaturated carboxylic acids in the medium of acetic acid.” Russian Journal of General Chemistry, vol. 79, no. 5, May. 2009, pp. 919-924. https://doi.org/10.1134/s1070363209050090.