Pleiades Publishing
Russian Journal of General Chemistry
,  том 83 ,  издание 10 ,  страницы 1888-1894

Acyloxy derivatives of trivalent phosphorus in amidoalkylation of hydrophosphoryl compounds

Тип публикации: Journal Article
Дата публикации: 2013-10-01
Pleiades Publishing
scimago Q4
wos Q4
БС2
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Краткое описание
In order to model the previously suggested mechanism of the P-C bond formation via the Arbuzov reaction, we have studied the interaction of diethylacylphosphite (prepared beforehand as well as generated in situ from tetraethylpyrophosphite) with the in situ generated acyliminium cation. Various conditions of in situ generation of acylphosphite derivatives of P(III) from hydrophosphoryl compounds and acyliminium ions from N,N′-alkylidenebiscarbamates have been investigated: solvent nature, acid catalyst, and the reagents mixing order). The results obtained have confirmed the suggested mechanism of three-component reaction of amidoalkylation of hydrophosphoryl compounds with the formation of P-C bond via the Arbuzov reaction of in situ formed intermediates.
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Journal of Organic Chemistry
Journal of Organic Chemistry, 1, 33.33%
Journal of Organic Chemistry
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Phosphorus, Sulfur and Silicon and the Related Elements
Phosphorus, Sulfur and Silicon and the Related Elements, 1, 33.33%
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Mendeleev Communications, 1, 33.33%
Mendeleev Communications
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Dmitriev M. E., Ragulin V. V. Acyloxy derivatives of trivalent phosphorus in amidoalkylation of hydrophosphoryl compounds // Russian Journal of General Chemistry. 2013. Vol. 83. No. 10. pp. 1888-1894.
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Dmitriev M. E., Ragulin V. V. Acyloxy derivatives of trivalent phosphorus in amidoalkylation of hydrophosphoryl compounds // Russian Journal of General Chemistry. 2013. Vol. 83. No. 10. pp. 1888-1894.
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TY - JOUR
DO - 10.1134/s1070363213100150
UR - https://doi.org/10.1134/s1070363213100150
TI - Acyloxy derivatives of trivalent phosphorus in amidoalkylation of hydrophosphoryl compounds
T2 - Russian Journal of General Chemistry
AU - Dmitriev, M E
AU - Ragulin, V V
PY - 2013
DA - 2013/10/01
PB - Pleiades Publishing
SP - 1888-1894
IS - 10
VL - 83
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2013_Dmitriev,
author = {M E Dmitriev and V V Ragulin},
title = {Acyloxy derivatives of trivalent phosphorus in amidoalkylation of hydrophosphoryl compounds},
journal = {Russian Journal of General Chemistry},
year = {2013},
volume = {83},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/s1070363213100150},
number = {10},
pages = {1888--1894},
doi = {10.1134/s1070363213100150}
}
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Dmitriev, M. E., and V V Ragulin. “Acyloxy derivatives of trivalent phosphorus in amidoalkylation of hydrophosphoryl compounds.” Russian Journal of General Chemistry, vol. 83, no. 10, Oct. 2013, pp. 1888-1894. https://doi.org/10.1134/s1070363213100150.