New Azepine-Furan Spirocyclic Structures in the Reaction of 4-Aroyl-1,2-dihydrobenzo[d]azepines and 2-Aroyl-4,5-dihydrophenanthreno[1,2-d]azepine with Formaldehyde
A A Zubenko
1
,
A S Morkovnik
2
,
L N Divaeva
2
,
V S Sochnev
2
,
O P Demidov
3
,
A N Bodryakov
1
,
L N Fetisov
1
,
K N Kononenko
1
,
M A Bodryakova
1
,
A I Klimenko
1
1
North-Caucasian Zonal Research Veterinary Institute, Novocherkassk, Russia
|
Publication type: Journal Article
Publication date: 2021-05-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
4-Aroyl-1,2-dihydrobenzo[d]azepines, as well as their phenanthro[1,2-d]azepine keto analogs, under the action of formaldehyde in the presence of acid-base catalysts, can undergo diastereoselective transformation into spirocyclic systems, containing two spiro-fused hetero rings – tetrahydroazepine and bifunctionalized tetrahydrofuran. This transformation is provided by a combination of azepine-azepine recyclization of substrates followed by spirocyclization of its products.
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Zubenko A. A. et al. New Azepine-Furan Spirocyclic Structures in the Reaction of 4-Aroyl-1,2-dihydrobenzo[d]azepines and 2-Aroyl-4,5-dihydrophenanthreno[1,2-d]azepine with Formaldehyde // Russian Journal of General Chemistry. 2021. Vol. 91. No. 5. pp. 792-798.
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Zubenko A. A., Morkovnik A. S., Divaeva L. N., Sochnev V. S., Demidov O. P., Bodryakov A. N., Fetisov L. N., Kononenko K. N., Bodryakova M. A., Klimenko A. I. New Azepine-Furan Spirocyclic Structures in the Reaction of 4-Aroyl-1,2-dihydrobenzo[d]azepines and 2-Aroyl-4,5-dihydrophenanthreno[1,2-d]azepine with Formaldehyde // Russian Journal of General Chemistry. 2021. Vol. 91. No. 5. pp. 792-798.
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TY - JOUR
DO - 10.1134/s1070363221050066
UR - https://doi.org/10.1134/s1070363221050066
TI - New Azepine-Furan Spirocyclic Structures in the Reaction of 4-Aroyl-1,2-dihydrobenzo[d]azepines and 2-Aroyl-4,5-dihydrophenanthreno[1,2-d]azepine with Formaldehyde
T2 - Russian Journal of General Chemistry
AU - Zubenko, A A
AU - Morkovnik, A S
AU - Divaeva, L N
AU - Sochnev, V S
AU - Demidov, O P
AU - Bodryakov, A N
AU - Fetisov, L N
AU - Kononenko, K N
AU - Bodryakova, M A
AU - Klimenko, A I
PY - 2021
DA - 2021/05/01
PB - Pleiades Publishing
SP - 792-798
IS - 5
VL - 91
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2021_Zubenko,
author = {A A Zubenko and A S Morkovnik and L N Divaeva and V S Sochnev and O P Demidov and A N Bodryakov and L N Fetisov and K N Kononenko and M A Bodryakova and A I Klimenko},
title = {New Azepine-Furan Spirocyclic Structures in the Reaction of 4-Aroyl-1,2-dihydrobenzo[d]azepines and 2-Aroyl-4,5-dihydrophenanthreno[1,2-d]azepine with Formaldehyde},
journal = {Russian Journal of General Chemistry},
year = {2021},
volume = {91},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134/s1070363221050066},
number = {5},
pages = {792--798},
doi = {10.1134/s1070363221050066}
}
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Zubenko, A. A., et al. “New Azepine-Furan Spirocyclic Structures in the Reaction of 4-Aroyl-1,2-dihydrobenzo[d]azepines and 2-Aroyl-4,5-dihydrophenanthreno[1,2-d]azepine with Formaldehyde.” Russian Journal of General Chemistry, vol. 91, no. 5, May. 2021, pp. 792-798. https://doi.org/10.1134/s1070363221050066.