Carboxylate Phosphabetaines Containing Chiral Carbon Atom: Synthesis and NMR Spectroscopy Data
S R Romanov
1
,
Yulia V Bakhtiyarova
1
,
M V Morozov
1
,
F Kh Karataeva
1
,
V V Klochkov
1
,
Irina V. Galkina
1
,
Vladimir I. Galkin
1
Publication type: Journal Article
Publication date: 2021-07-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
The nucleophilic addition reactions of tertiary phosphines and unsaturated carboxylic acids have led to the formation of mono- and dicarboxylate phosphabetaines containing an asymmetric carbon atom. The data of 1D and 2D NMR spectroscopy have revealed the presence of diastereotopic geminal protons of the CH2 group adjacent to the chiral center in the obtained compounds. The values of spin-spin coupling constants of the vicinal hydrogen atoms have coincided with the dihedral angles values (X-ray diffraction analysis data).
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Total citations:
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Citations from 2025:
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(16.67%)
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Romanov S. R. et al. Carboxylate Phosphabetaines Containing Chiral Carbon Atom: Synthesis and NMR Spectroscopy Data // Russian Journal of General Chemistry. 2021. Vol. 91. No. 7. pp. 1333-1341.
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Romanov S. R., Bakhtiyarova Y. V., Morozov M. V., Karataeva F. Kh., Klochkov V. V., Galkina I. V., Galkin V. I. Carboxylate Phosphabetaines Containing Chiral Carbon Atom: Synthesis and NMR Spectroscopy Data // Russian Journal of General Chemistry. 2021. Vol. 91. No. 7. pp. 1333-1341.
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RIS
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TY - JOUR
DO - 10.1134/s1070363221070112
UR - https://doi.org/10.1134/s1070363221070112
TI - Carboxylate Phosphabetaines Containing Chiral Carbon Atom: Synthesis and NMR Spectroscopy Data
T2 - Russian Journal of General Chemistry
AU - Romanov, S R
AU - Bakhtiyarova, Yulia V
AU - Morozov, M V
AU - Karataeva, F Kh
AU - Klochkov, V V
AU - Galkina, Irina V.
AU - Galkin, Vladimir I.
PY - 2021
DA - 2021/07/01
PB - Pleiades Publishing
SP - 1333-1341
IS - 7
VL - 91
SN - 1070-3632
SN - 1608-3350
ER -
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BibTex (up to 50 authors)
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@article{2021_Romanov,
author = {S R Romanov and Yulia V Bakhtiyarova and M V Morozov and F Kh Karataeva and V V Klochkov and Irina V. Galkina and Vladimir I. Galkin},
title = {Carboxylate Phosphabetaines Containing Chiral Carbon Atom: Synthesis and NMR Spectroscopy Data},
journal = {Russian Journal of General Chemistry},
year = {2021},
volume = {91},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/s1070363221070112},
number = {7},
pages = {1333--1341},
doi = {10.1134/s1070363221070112}
}
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MLA
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Romanov, S. R., et al. “Carboxylate Phosphabetaines Containing Chiral Carbon Atom: Synthesis and NMR Spectroscopy Data.” Russian Journal of General Chemistry, vol. 91, no. 7, Jul. 2021, pp. 1333-1341. https://doi.org/10.1134/s1070363221070112.
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