Influence of Viscosity of Compositions Based on Dimethacrylate Esters on Kinetics of Their Photopolymerization Initiated by 9,10-Phenanthrenequinone
Publication type: Journal Article
Publication date: 2018-11-01
scimago Q3
wos Q4
SJR: 0.234
CiteScore: 1.8
Impact factor: 1.0
ISSN: 15600904, 15556123
Materials Chemistry
Ceramics and Composites
Polymers and Plastics
Abstract
The kinetics of photopolymerization of compositions based on dimethacrylic oligomers in which the viscosity was varied from 3.1 to 376.7 cSt was investigated (initiator 9,10-phenanthrenequinone) under the influence of visible light. Triethyleneglycol dimethacrylate and dimethacrylates OCM-2 and MDPh-2 were used, as well as solvents methanol and butanol-1. The dependences of the viscosity of dimethacrylate–alcohol compositions on the concentration of components were determined. It was shown that the photoreduction rate of 9,10-phenanthrenequinone in dimethacrylate OCM-2 decreases with the alcohol and acetonitrile addition. It was found that, at the initial stages of the reaction, the dependence of the reduced photopolymerization rate on the initial viscosity of the compositions is described by a saturation curve with the plateau at a viscosity of 80 cSt or more.
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Zakharina M. Yu. et al. Influence of Viscosity of Compositions Based on Dimethacrylate Esters on Kinetics of Their Photopolymerization Initiated by 9,10-Phenanthrenequinone // Polymer Science - Series B. 2018. Vol. 60. No. 6. pp. 708-716.
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Zakharina M. Yu., Chechet Yu. V., Shurygina M. P., Chesnokov S. A. Influence of Viscosity of Compositions Based on Dimethacrylate Esters on Kinetics of Their Photopolymerization Initiated by 9,10-Phenanthrenequinone // Polymer Science - Series B. 2018. Vol. 60. No. 6. pp. 708-716.
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TY - JOUR
DO - 10.1134/s1560090418060131
UR - http://link.springer.com/10.1134/S1560090418060131
TI - Influence of Viscosity of Compositions Based on Dimethacrylate Esters on Kinetics of Their Photopolymerization Initiated by 9,10-Phenanthrenequinone
T2 - Polymer Science - Series B
AU - Zakharina, M Yu
AU - Chechet, Yu V
AU - Shurygina, M P
AU - Chesnokov, S. A.
PY - 2018
DA - 2018/11/01
PB - Pleiades Publishing
SP - 708-716
IS - 6
VL - 60
SN - 1560-0904
SN - 1555-6123
ER -
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@article{2018_Zakharina,
author = {M Yu Zakharina and Yu V Chechet and M P Shurygina and S. A. Chesnokov},
title = {Influence of Viscosity of Compositions Based on Dimethacrylate Esters on Kinetics of Their Photopolymerization Initiated by 9,10-Phenanthrenequinone},
journal = {Polymer Science - Series B},
year = {2018},
volume = {60},
publisher = {Pleiades Publishing},
month = {nov},
url = {http://link.springer.com/10.1134/S1560090418060131},
number = {6},
pages = {708--716},
doi = {10.1134/s1560090418060131}
}
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Zakharina, M. Yu., et al. “Influence of Viscosity of Compositions Based on Dimethacrylate Esters on Kinetics of Their Photopolymerization Initiated by 9,10-Phenanthrenequinone.” Polymer Science - Series B, vol. 60, no. 6, Nov. 2018, pp. 708-716. http://link.springer.com/10.1134/S1560090418060131.