Determination of Monomer Reactivity Ratios in Controlled Copolymerization of Acrylonitrile with Unsaturated Methyl Esters
Publication type: Journal Article
Publication date: 2020-05-01
scimago Q3
wos Q4
SJR: 0.234
CiteScore: 1.8
Impact factor: 1.0
ISSN: 15600904, 15556123
Materials Chemistry
Ceramics and Composites
Polymers and Plastics
Abstract
This paper reports the investigation of copolymerization of acrylonitrile with methyl acrylate, dimethyl maleate, dimethyl fumarate and dimethyl itaconate via atom transfer radical polymerization mechanism using copper bromide as a catalyst in combination with tris(2-pyridylmethyl)amine as a ligand. The reactivity ratios of monomers were evaluated using the Finemann–Ross and Kelen–Tudos methods basing on the copolymer composition determined by 1H NMR spectroscopy. It was found that reversible deactivation mechanism has no significant influence on the monomer reactivity ratios. It was found that among the tested comonomers methyl acrylate and dimethyl itaconate seem to be the most suitable ones for obtaining well-defined copolymers of acrylonitrile.
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Stakhi S. A., Grishin D. F., Grishin I. D. Determination of Monomer Reactivity Ratios in Controlled Copolymerization of Acrylonitrile with Unsaturated Methyl Esters // Polymer Science - Series B. 2020. Vol. 62. No. 3. pp. 169-175.
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Stakhi S. A., Grishin D. F., Grishin I. D. Determination of Monomer Reactivity Ratios in Controlled Copolymerization of Acrylonitrile with Unsaturated Methyl Esters // Polymer Science - Series B. 2020. Vol. 62. No. 3. pp. 169-175.
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TY - JOUR
DO - 10.1134/s1560090420030148
UR - https://doi.org/10.1134/s1560090420030148
TI - Determination of Monomer Reactivity Ratios in Controlled Copolymerization of Acrylonitrile with Unsaturated Methyl Esters
T2 - Polymer Science - Series B
AU - Stakhi, Sergey A
AU - Grishin, Dmitry F.
AU - Grishin, Ivan D
PY - 2020
DA - 2020/05/01
PB - Pleiades Publishing
SP - 169-175
IS - 3
VL - 62
SN - 1560-0904
SN - 1555-6123
ER -
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BibTex (up to 50 authors)
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@article{2020_Stakhi,
author = {Sergey A Stakhi and Dmitry F. Grishin and Ivan D Grishin},
title = {Determination of Monomer Reactivity Ratios in Controlled Copolymerization of Acrylonitrile with Unsaturated Methyl Esters},
journal = {Polymer Science - Series B},
year = {2020},
volume = {62},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134/s1560090420030148},
number = {3},
pages = {169--175},
doi = {10.1134/s1560090420030148}
}
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MLA
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Stakhi, Sergey A., et al. “Determination of Monomer Reactivity Ratios in Controlled Copolymerization of Acrylonitrile with Unsaturated Methyl Esters.” Polymer Science - Series B, vol. 62, no. 3, May. 2020, pp. 169-175. https://doi.org/10.1134/s1560090420030148.