A study of the radical polymerization of styrene in the presence of ferrocene
Publication type: Journal Article
Publication date: 2011-02-01
scimago Q4
SJR: 0.244
CiteScore: 2.6
Impact factor: —
ISSN: 19907931, 19907923
Physical and Theoretical Chemistry
Abstract
Reactions that occurred during the radical polymerization of styrene in the presence of ferrocene were analyzed by the B3LYP/6-31G(d, p) method of density functional theory. The formation of the Fe-C bond between the iron atom of ferrocene and polystyrene radical (R·) was found to be energetically unfavorable, and the polystyrene chain growth reaction in the coordination sphere of the iron atom by the insertion of the monomer at the Fe-C bond was characterized by a high activation energy. Conversely, the addition of R· to the ferrocene cyclopentadienyl ring occurred with the release of energy. Indications of termination-free styrene polymerization in the presence of ferrocene experimentally observed earlier were explained in terms of reversible inhibition concepts.
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Total citations:
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Citations from 2025:
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(33.33%)
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GOST
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Friesen A. K. et al. A study of the radical polymerization of styrene in the presence of ferrocene // Russian Journal of Physical Chemistry B. 2011. Vol. 5. No. 1. pp. 131-138.
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Friesen A. K., Khursan S. L., Kolesov S. V., Monakov Yu. B. A study of the radical polymerization of styrene in the presence of ferrocene // Russian Journal of Physical Chemistry B. 2011. Vol. 5. No. 1. pp. 131-138.
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RIS
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TY - JOUR
DO - 10.1134/s1990793111010040
UR - https://doi.org/10.1134/s1990793111010040
TI - A study of the radical polymerization of styrene in the presence of ferrocene
T2 - Russian Journal of Physical Chemistry B
AU - Friesen, A K
AU - Khursan, S L
AU - Kolesov, S. V.
AU - Monakov, Yu B
PY - 2011
DA - 2011/02/01
PB - Pleiades Publishing
SP - 131-138
IS - 1
VL - 5
SN - 1990-7931
SN - 1990-7923
ER -
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BibTex (up to 50 authors)
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@article{2011_Friesen,
author = {A K Friesen and S L Khursan and S. V. Kolesov and Yu B Monakov},
title = {A study of the radical polymerization of styrene in the presence of ferrocene},
journal = {Russian Journal of Physical Chemistry B},
year = {2011},
volume = {5},
publisher = {Pleiades Publishing},
month = {feb},
url = {https://doi.org/10.1134/s1990793111010040},
number = {1},
pages = {131--138},
doi = {10.1134/s1990793111010040}
}
Cite this
MLA
Copy
Friesen, A. K., et al. “A study of the radical polymerization of styrene in the presence of ferrocene.” Russian Journal of Physical Chemistry B, vol. 5, no. 1, Feb. 2011, pp. 131-138. https://doi.org/10.1134/s1990793111010040.