Collection of Czechoslovak Chemical Communications
,  volume 55 ,  issue 6 ,  pages 1630-1634

Reactions of N-tricyanovinylamines with thiols in aqueous solutions

Publication type: Journal Article
Publication date: 2010-02-11
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00100765, 12126950
General Chemistry
Abstract

Kinetics of reactions between N-substituted tricyanovinylamines and thiols, where primarily reduction of the C=C double bond takes place, was investigated under conditions adequate to physiological ones. The reaction rates did not depend either on the type of the reacting thiol, or on the pH of the medium, but they decreased with the increasing pKa value of the imino group. A quantitative conversion of the thiol peptide glutathione to its oxidized form was evidenced.

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GOST |
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GOST Copy
Podhradský D., Paulíková H., Imrich J. Reactions of N-tricyanovinylamines with thiols in aqueous solutions // Collection of Czechoslovak Chemical Communications. 2010. Vol. 55. No. 6. pp. 1630-1634.
GOST all authors (up to 50) Copy
Podhradský D., Paulíková H., Imrich J. Reactions of N-tricyanovinylamines with thiols in aqueous solutions // Collection of Czechoslovak Chemical Communications. 2010. Vol. 55. No. 6. pp. 1630-1634.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1135/cccc19901630
UR - https://doi.org/10.1135/cccc19901630
TI - Reactions of N-tricyanovinylamines with thiols in aqueous solutions
T2 - Collection of Czechoslovak Chemical Communications
AU - Podhradský, Dušan
AU - Paulíková, Helena
AU - Imrich, Ján
PY - 2010
DA - 2010/02/11
PB - Institute of Organic Chemistry & Biochemistry
SP - 1630-1634
IS - 6
VL - 55
SN - 0010-0765
SN - 1212-6950
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2010_Podhradský,
author = {Dušan Podhradský and Helena Paulíková and Ján Imrich},
title = {Reactions of N-tricyanovinylamines with thiols in aqueous solutions},
journal = {Collection of Czechoslovak Chemical Communications},
year = {2010},
volume = {55},
publisher = {Institute of Organic Chemistry & Biochemistry},
month = {feb},
url = {https://doi.org/10.1135/cccc19901630},
number = {6},
pages = {1630--1634},
doi = {10.1135/cccc19901630}
}
MLA
Cite this
MLA Copy
Podhradský, Dušan, et al. “Reactions of N-tricyanovinylamines with thiols in aqueous solutions.” Collection of Czechoslovak Chemical Communications, vol. 55, no. 6, Feb. 2010, pp. 1630-1634. https://doi.org/10.1135/cccc19901630.