volume 67 issue 5 pages 665-678

9-Isothiocyanatoanthracene as a Versatile Starting Compound in the Chemistry of Anthracen-9-yl Derivatives

Ladislav Janovec
Gejza Suchár
Ján Imrich
Pavol Kristian
Vlasta Sasinková
Juraj Alföldi
Erik Sedlák
Publication typeJournal Article
Publication date2002-07-28
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ISSN00100765, 12126950
General Chemistry
Abstract

The synthesis, structure and reactivity of 9-isothiocyanatoanthracene (5) likewise the conformation of the corresponding thioureas (6a-6i) have been studied. The 13C NMR substituent chemical shift values of the NCS group and correlations between spectral parameters (IR, NMR) and rate constans of reactions of 5, acridin-9-yl (14), phenyl (15) and benzoyl isothiocyanate (16) with butylamine were found. Significant increase of the fluorescence of the synthesized anthracenylthioureas with amino acid rests refers to the possibility to use 5 as potential biomarker.

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Janovec L. et al. 9-Isothiocyanatoanthracene as a Versatile Starting Compound in the Chemistry of Anthracen-9-yl Derivatives // Collection of Czechoslovak Chemical Communications. 2002. Vol. 67. No. 5. pp. 665-678.
GOST all authors (up to 50) Copy
Janovec L., Suchár G., Imrich J., Kristian P., Sasinková V., Alföldi J., Sedlák E. 9-Isothiocyanatoanthracene as a Versatile Starting Compound in the Chemistry of Anthracen-9-yl Derivatives // Collection of Czechoslovak Chemical Communications. 2002. Vol. 67. No. 5. pp. 665-678.
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RIS Copy
TY - JOUR
DO - 10.1135/cccc20020665
UR - https://doi.org/10.1135/cccc20020665
TI - 9-Isothiocyanatoanthracene as a Versatile Starting Compound in the Chemistry of Anthracen-9-yl Derivatives
T2 - Collection of Czechoslovak Chemical Communications
AU - Janovec, Ladislav
AU - Suchár, Gejza
AU - Imrich, Ján
AU - Kristian, Pavol
AU - Sasinková, Vlasta
AU - Alföldi, Juraj
AU - Sedlák, Erik
PY - 2002
DA - 2002/07/28
PB - Institute of Organic Chemistry & Biochemistry
SP - 665-678
IS - 5
VL - 67
SN - 0010-0765
SN - 1212-6950
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2002_Janovec,
author = {Ladislav Janovec and Gejza Suchár and Ján Imrich and Pavol Kristian and Vlasta Sasinková and Juraj Alföldi and Erik Sedlák},
title = {9-Isothiocyanatoanthracene as a Versatile Starting Compound in the Chemistry of Anthracen-9-yl Derivatives},
journal = {Collection of Czechoslovak Chemical Communications},
year = {2002},
volume = {67},
publisher = {Institute of Organic Chemistry & Biochemistry},
month = {jul},
url = {https://doi.org/10.1135/cccc20020665},
number = {5},
pages = {665--678},
doi = {10.1135/cccc20020665}
}
MLA
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MLA Copy
Janovec, Ladislav, et al. “9-Isothiocyanatoanthracene as a Versatile Starting Compound in the Chemistry of Anthracen-9-yl Derivatives.” Collection of Czechoslovak Chemical Communications, vol. 67, no. 5, Jul. 2002, pp. 665-678. https://doi.org/10.1135/cccc20020665.