Canadian Journal of Chemistry, volume 58, issue 8, pages 815-822
Synthesis, X-ray structure determination, and formation of 3,4,5-trichloroguaiacol occurring in kraft pulp spent bleach liquors
K Lindström
,
F Osterberg
,
F. Österberg
Publication type: Journal Article
Publication date: 1980-04-15
Journal:
Canadian Journal of Chemistry
scimago Q3
SJR: 0.223
CiteScore: 1.9
Impact factor: 1.1
ISSN: 00084042, 14803291
DOI:
10.1139/v80-127
General Chemistry
Catalysis
Organic Chemistry
Abstract
3,4,5-Trichloroguaiacol, which is formed during bleaching of chemical pulp and shown to bioaccumulate in fish, has been synthesized. The structure of the compound has been determined by means of X-ray analysis. The values of the 13C nmr chemical shifts and melting point differ from those previously reported. A reaction mechanism is suggested for the formation of 3,4,5- and 4,5,6-trichloroguaiacol.
Found
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