Canadian Journal of Chemistry

, том 40 , издание 2 , страницы 283-288

CHEMISTRY OF THE TRIFLUOROMETHYL GROUP: PART IV. DIPHENYLTRIFLUOROMETHYLPHOSPHINE AND COMPLEX FORMATION BY PHENYLTRIFLUOROMETHYLPHOSPHINES

Тип публикации: Journal Article

Дата публикации: 1962-02-01

Canadian Science Publishing

Canadian Journal of Chemistry

SCImago Q3

WOS Q4

БС3

SJR: 0.28

CiteScore: 2.1

Impact factor: 1

ISSN: 00084042, 14803291

DOI: 10.1139/v62-046

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General Chemistry

Catalysis

Organic Chemistry

Краткое описание

Three methods of preparing diphenyltrifluoromethylphosphine are described. The hydrolysis of the phosphine to diphenylphosphinic acid and fluoroform, and the formation of dibromo-and diiodo-phosphoranes from the phosphine are reported. The adducts (C₆H₅)₃P_•BF₃ and (C₆H₅)₂CF₃P_•BF₃ are described and the latter is found to be the less stable. With platinum (II) chloride, the complexes trans-[(C₆H₅)₂PCF₃]₂PtCl₂ and trans-[C₆H₅PCF₃)₂]₂PtCl₂ are formed. The properties of the BF₃ adducts and PtCl₂ complexes are interpreted in terms of the electronegativity and size of the trifluoromethyl group.

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Beg M. A. A., CLARK H. C. CHEMISTRY OF THE TRIFLUOROMETHYL GROUP: PART IV. DIPHENYLTRIFLUOROMETHYLPHOSPHINE AND COMPLEX FORMATION BY PHENYLTRIFLUOROMETHYLPHOSPHINES // Canadian Journal of Chemistry. 1962. Vol. 40. No. 2. pp. 283-288.

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TY - JOUR

DO - 10.1139/v62-046

UR - https://doi.org/10.1139/v62-046

TI - CHEMISTRY OF THE TRIFLUOROMETHYL GROUP: PART IV. DIPHENYLTRIFLUOROMETHYLPHOSPHINE AND COMPLEX FORMATION BY PHENYLTRIFLUOROMETHYLPHOSPHINES

T2 - Canadian Journal of Chemistry

AU - Beg, M. A. A.

AU - CLARK, H. C.

PY - 1962

DA - 1962/02/01

PB - Canadian Science Publishing

SP - 283-288

IS - 2

VL - 40

SN - 0008-4042

SN - 1480-3291

ER -

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@article{1962_Beg,

author = {M. A. A. Beg and H. C. CLARK},

title = {CHEMISTRY OF THE TRIFLUOROMETHYL GROUP: PART IV. DIPHENYLTRIFLUOROMETHYLPHOSPHINE AND COMPLEX FORMATION BY PHENYLTRIFLUOROMETHYLPHOSPHINES},

journal = {Canadian Journal of Chemistry},

year = {1962},

volume = {40},

publisher = {Canadian Science Publishing},

month = {feb},

url = {https://doi.org/10.1139/v62-046},

number = {2},

pages = {283--288},

doi = {10.1139/v62-046}

}

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Beg, M. A. A., and H. C. CLARK. “CHEMISTRY OF THE TRIFLUOROMETHYL GROUP: PART IV. DIPHENYLTRIFLUOROMETHYLPHOSPHINE AND COMPLEX FORMATION BY PHENYLTRIFLUOROMETHYLPHOSPHINES.” Canadian Journal of Chemistry, vol. 40, no. 2, Feb. 1962, pp. 283-288. https://doi.org/10.1139/v62-046.

Издатель

Canadian Science Publishing

Журнал

Canadian Journal of Chemistry

SCImago Q3

WOS Q4

БС3

SJR

0.28

CiteScore

2.1

Impact factor

ISSN

00084042 (Print)

14803291 (Electronic)

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