Canadian Journal of Chemistry, volume 52, issue 8, pages 1248-1252
An Electron Spin Resonance Study of Radicals Formed by γ-Irradiation of 1-Substituted 5-Nitro-amino and 5-Nitroso-aminotetrazoles
Publication type: Journal Article
Publication date: 1974-04-15
Journal:
Canadian Journal of Chemistry
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor: 1.1
ISSN: 00084042, 14803291
DOI:
10.1139/v74-194
General Chemistry
Catalysis
Organic Chemistry
Abstract
γ-Irradiation of 1-methyl-5-methylnitro-aminotetrazole 1 and 1-methyl-5-nitro-aminotetrazole 2 resulted in cleavage of the exocyclic N—N bond giving only one detectable radical (NO2•) in each case. The stability and motion of the NO2• radicals formed in these systems was studied. The NO2• radical obtained from compound 1 was immobile in the lattice while that obtained from compound 2 was rotating about the y-axis. Irradiation of 1-methyl-5-methyl-nitroso-aminotetrazole 3 and 1-phenyl-5-nitroso-aminotetrazole 4 did not give a simple N—N bond cleavage and radicals which could not be fully identified were encountered. The radical obtained from compound 3 appeared to be a nitroxide radical and that obtained from compound 4 appeared to arise from electron capture by the nitrosamino moiety.
Top-30
Citations by journals
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1
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Chemischer Informationsdienst
1 publication, 33.33%
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Advances in Heterocyclic Chemistry
1 publication, 33.33%
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Russian Chemical Reviews
1 publication, 33.33%
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1
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Citations by publishers
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1
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Wiley
1 publication, 33.33%
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Elsevier
1 publication, 33.33%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 33.33%
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1
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Catton R. C., Butler R. N. An Electron Spin Resonance Study of Radicals Formed by γ-Irradiation of 1-Substituted 5-Nitro-amino and 5-Nitroso-aminotetrazoles // Canadian Journal of Chemistry. 1974. Vol. 52. No. 8. pp. 1248-1252.
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Catton R. C., Butler R. N. An Electron Spin Resonance Study of Radicals Formed by γ-Irradiation of 1-Substituted 5-Nitro-amino and 5-Nitroso-aminotetrazoles // Canadian Journal of Chemistry. 1974. Vol. 52. No. 8. pp. 1248-1252.
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TY - JOUR
DO - 10.1139/v74-194
UR - https://doi.org/10.1139/v74-194
TI - An Electron Spin Resonance Study of Radicals Formed by γ-Irradiation of 1-Substituted 5-Nitro-amino and 5-Nitroso-aminotetrazoles
T2 - Canadian Journal of Chemistry
AU - Catton, Richard C.
AU - Butler, Richard N.
PY - 1974
DA - 1974/04/15 00:00:00
PB - Canadian Science Publishing
SP - 1248-1252
IS - 8
VL - 52
SN - 0008-4042
SN - 1480-3291
ER -
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@article{1974_Catton,
author = {Richard C. Catton and Richard N. Butler},
title = {An Electron Spin Resonance Study of Radicals Formed by γ-Irradiation of 1-Substituted 5-Nitro-amino and 5-Nitroso-aminotetrazoles},
journal = {Canadian Journal of Chemistry},
year = {1974},
volume = {52},
publisher = {Canadian Science Publishing},
month = {apr},
url = {https://doi.org/10.1139/v74-194},
number = {8},
pages = {1248--1252},
doi = {10.1139/v74-194}
}
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MLA
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Catton, Richard C., and Richard N. Butler. “An Electron Spin Resonance Study of Radicals Formed by γ-Irradiation of 1-Substituted 5-Nitro-amino and 5-Nitroso-aminotetrazoles.” Canadian Journal of Chemistry, vol. 52, no. 8, Apr. 1974, pp. 1248-1252. https://doi.org/10.1139/v74-194.