The products of hydrolysis of cyclic orthoesters as a function of pH and the theory of stereoelectronic control
Тип публикации: Journal Article
Дата публикации: 1985-09-01
SCImago Q3
WOS Q4
БС3
SJR: 0.28
CiteScore: 2.1
Impact factor: 1
ISSN: 00084042, 14803291
General Chemistry
Catalysis
Organic Chemistry
Краткое описание
The acid hydrolysis of cyclic orthoesters 1, 3–6 (R = Me), and 2 (R = Me and Et) as a function of pH was studied. The bicyclic orthoester 5 yields mainly the hydroxy-ester (less than 5% lactone), and this result is essentially independent of pH. For the other orthoesters, the relative percentage of products differs for each case and varies with pH. At pH ≤ 3, the percentage of lactone is always larger than at pH > 3. These results are explained on the basis of the stereoelectronic theory for the cleavage of tetrahedral intermediates.
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ГОСТ
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Deslongchamps P., Lessard J., Nadeau Y. The products of hydrolysis of cyclic orthoesters as a function of pH and the theory of stereoelectronic control // Canadian Journal of Chemistry. 1985. Vol. 63. No. 9. pp. 2485-2492.
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Deslongchamps P., Lessard J., Nadeau Y. The products of hydrolysis of cyclic orthoesters as a function of pH and the theory of stereoelectronic control // Canadian Journal of Chemistry. 1985. Vol. 63. No. 9. pp. 2485-2492.
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RIS
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TY - JOUR
DO - 10.1139/v85-412
UR - https://doi.org/10.1139/v85-412
TI - The products of hydrolysis of cyclic orthoesters as a function of pH and the theory of stereoelectronic control
T2 - Canadian Journal of Chemistry
AU - Deslongchamps, Pierre
AU - Lessard, Jean
AU - Nadeau, Yves
PY - 1985
DA - 1985/09/01
PB - Canadian Science Publishing
SP - 2485-2492
IS - 9
VL - 63
SN - 0008-4042
SN - 1480-3291
ER -
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BibTex (до 50 авторов)
Скопировать
@article{1985_Deslongchamps,
author = {Pierre Deslongchamps and Jean Lessard and Yves Nadeau},
title = {The products of hydrolysis of cyclic orthoesters as a function of pH and the theory of stereoelectronic control},
journal = {Canadian Journal of Chemistry},
year = {1985},
volume = {63},
publisher = {Canadian Science Publishing},
month = {sep},
url = {https://doi.org/10.1139/v85-412},
number = {9},
pages = {2485--2492},
doi = {10.1139/v85-412}
}
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MLA
Скопировать
Deslongchamps, Pierre, et al. “The products of hydrolysis of cyclic orthoesters as a function of pH and the theory of stereoelectronic control.” Canadian Journal of Chemistry, vol. 63, no. 9, Sep. 1985, pp. 2485-2492. https://doi.org/10.1139/v85-412.
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