Annual Review of Materials Science, volume 30, issue 1, pages 545-610
Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies
1
IBM T. J. Watson Research Center, Yorktown Heights, NewYork 10598;
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Publication type: Journal Article
Publication date: 2000-08-25
Journal:
Annual Review of Materials Science
Quartile SCImago
— Quartile WOS
—
Impact factor: —
ISSN: 00846600
General Materials Science
Abstract
▪ Abstract Solution phase syntheses and size-selective separation methods to prepare semiconductor and metal nanocrystals, tunable in size from ∼1 to 20 nm and monodisperse to ≤5%, are presented. Preparation of monodisperse samples enables systematic characterization of the structural, electronic, and optical properties of materials as they evolve from molecular to bulk in the nanometer size range. Sample uniformity makes it possible to manipulate nanocrystals into close-packed, glassy, and ordered nanocrystal assemblies (superlattices, colloidal crystals, supercrystals). Rigorous structural characterization is critical to understanding the electronic and optical properties of both nanocrystals and their assemblies. At inter-particle separations 5–100 Å, dipole-dipole interactions lead to energy transfer between neighboring nanocrystals, and electronic tunneling between proximal nanocrystals gives rise to dark and photoconductivity. At separations <5 Å, exchange interactions cause otherwise insulating assemblies to become semiconducting, metallic, or superconducting depending on nanocrystal composition. Tailoring the size and composition of the nanocrystals and the length and electronic structure of the matrix may tune the properties of nanocrystal solid-state materials.
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Citations by publishers
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Murray C. B., Kagan C. R., Bawendi M. G. Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies // Annual Review of Materials Science. 2000. Vol. 30. No. 1. pp. 545-610.
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Murray C. B., Kagan C. R., Bawendi M. G. Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies // Annual Review of Materials Science. 2000. Vol. 30. No. 1. pp. 545-610.
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TY - JOUR
DO - 10.1146/annurev.matsci.30.1.545
UR - https://doi.org/10.1146/annurev.matsci.30.1.545
TI - Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies
T2 - Annual Review of Materials Science
AU - Murray, C. B.
AU - Kagan, C R
AU - Bawendi, M G
PY - 2000
DA - 2000/08/25 00:00:00
PB - Annual Reviews
SP - 545-610
IS - 1
VL - 30
SN - 0084-6600
ER -
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@article{2000_Murray,
author = {C. B. Murray and C R Kagan and M G Bawendi},
title = {Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies},
journal = {Annual Review of Materials Science},
year = {2000},
volume = {30},
publisher = {Annual Reviews},
month = {aug},
url = {https://doi.org/10.1146/annurev.matsci.30.1.545},
number = {1},
pages = {545--610},
doi = {10.1146/annurev.matsci.30.1.545}
}
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Murray, C. B., et al. “Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies.” Annual Review of Materials Science, vol. 30, no. 1, Aug. 2000, pp. 545-610. https://doi.org/10.1146/annurev.matsci.30.1.545.