LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles
Publication type: Journal Article
Publication date: 2007-01-17
scimago Q1
wos Q2
SJR: 0.774
CiteScore: 6.1
Impact factor: 3.3
ISSN: 00134651, 19457111
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Renewable Energy, Sustainability and the Environment
Abstract
To improve the LSM-YSZ cathode performance of intermediate temperature solid oxide fuel cells (SOFCs), Sm0.6Sr0.4CoO3-sigma (SSC) perovskite nanoparticles are incorporated into the cathodes by a reaction-infiltration process. The SSC particles are {approx}20 to 80nm in diameter, and intimately adhere to the pore walls of the preformed LSM-YSZ cathodes. The SSC particles dramatically enhance single-cell performance with a 97 percent H2+3 percent H2O fuel, between 600 C and 800 C. Consideration of a simplified TPB (triple phase boundary) reaction geometry indicates that the enhancement may be attributed to the high electrocatalytic activity of SSC for electrochemical reduction of oxygen in a region that can be located a small distance away from the strict triple phase boundaries. The implication of this work for developing high-performance electrodes is also discussed.
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68
Total citations:
68
Citations from 2024:
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(7.35%)
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GOST
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Lu C. et al. LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles // Journal of the Electrochemical Society. 2007. Vol. 153. No. 6. p. A1115.
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Lu C., Sholklapper T. Z., Jacobson C. P., Visco S. J., De Jonghe L. C. LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles // Journal of the Electrochemical Society. 2007. Vol. 153. No. 6. p. A1115.
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RIS
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TY - JOUR
DO - 10.1149/1.2192733
UR - https://doi.org/10.1149/1.2192733
TI - LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles
T2 - Journal of the Electrochemical Society
AU - Lu, Chun-Lin
AU - Sholklapper, Tal Z.
AU - Jacobson, Craig P
AU - Visco, Steven J.
AU - De Jonghe, Lutgard C.
PY - 2007
DA - 2007/01/17
PB - The Electrochemical Society
SP - A1115
IS - 6
VL - 153
SN - 0013-4651
SN - 1945-7111
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2007_Lu,
author = {Chun-Lin Lu and Tal Z. Sholklapper and Craig P Jacobson and Steven J. Visco and Lutgard C. De Jonghe},
title = {LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles},
journal = {Journal of the Electrochemical Society},
year = {2007},
volume = {153},
publisher = {The Electrochemical Society},
month = {jan},
url = {https://doi.org/10.1149/1.2192733},
number = {6},
pages = {A1115},
doi = {10.1149/1.2192733}
}
Cite this
MLA
Copy
Lu, Chun-Lin, et al. “LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles.” Journal of the Electrochemical Society, vol. 153, no. 6, Jan. 2007, p. A1115. https://doi.org/10.1149/1.2192733.