Solid Oxide Electrolysis Cells: Degradation at High Current Densities
Publication type: Journal Article
Publication date: 2010-07-08
scimago Q1
wos Q2
SJR: 0.774
CiteScore: 6.1
Impact factor: 3.3
ISSN: 00134651, 19457111
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Renewable Energy, Sustainability and the Environment
Abstract
The degradation of Ni/yttria-stabilized zirconia (YSZ)-based solid oxide electrolysis cells operated at high current densities was studied. The degradation was examined at 850 degrees C, at current densities of -1.0, -1.5, and -2.0 A/cm(2), with a 50:50 (H(2)O:H(2)) gas supplied to the Ni/YSZ hydrogen electrode and oxygen supplied to the lanthanum, strontium manganite (LSM)/YSZ oxygen electrode. Electrode polarization resistance degradation is not directly related to the applied current density but rather a consequence of adsorbed impurities in the Ni/YSZ hydrogen electrode. However, the ohmic resistance degradation increases with applied current density. The ohmic resistance degradation is attributed to oxygen formation in the YSZ electrolyte grain boundaries near the oxygen electrode/electrolyte interface. (C) 2010 The Electrochemical Society. [DOI:10.1149/1.3447752] All rights reserved.
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Knibbe R. et al. Solid Oxide Electrolysis Cells: Degradation at High Current Densities // Journal of the Electrochemical Society. 2010. Vol. 157. No. 8. p. B1209.
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Knibbe R., Traulsen M. L., Hauch A., Ebbesen S. D., Mogensen M. Solid Oxide Electrolysis Cells: Degradation at High Current Densities // Journal of the Electrochemical Society. 2010. Vol. 157. No. 8. p. B1209.
Cite this
RIS
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TY - JOUR
DO - 10.1149/1.3447752
UR - https://doi.org/10.1149/1.3447752
TI - Solid Oxide Electrolysis Cells: Degradation at High Current Densities
T2 - Journal of the Electrochemical Society
AU - Knibbe, Ruth
AU - Traulsen, Marie Lund
AU - Hauch, Anne
AU - Ebbesen, Sune Dalgaard
AU - Mogensen, Mogens
PY - 2010
DA - 2010/07/08
PB - The Electrochemical Society
SP - B1209
IS - 8
VL - 157
SN - 0013-4651
SN - 1945-7111
ER -
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BibTex (up to 50 authors)
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@article{2010_Knibbe,
author = {Ruth Knibbe and Marie Lund Traulsen and Anne Hauch and Sune Dalgaard Ebbesen and Mogens Mogensen},
title = {Solid Oxide Electrolysis Cells: Degradation at High Current Densities},
journal = {Journal of the Electrochemical Society},
year = {2010},
volume = {157},
publisher = {The Electrochemical Society},
month = {jul},
url = {https://doi.org/10.1149/1.3447752},
number = {8},
pages = {B1209},
doi = {10.1149/1.3447752}
}
Cite this
MLA
Copy
Knibbe, Ruth, et al. “Solid Oxide Electrolysis Cells: Degradation at High Current Densities.” Journal of the Electrochemical Society, vol. 157, no. 8, Jul. 2010, p. B1209. https://doi.org/10.1149/1.3447752.