Substituted o-Aminophenols as Redox-Mediators in the Thiol Oxidation to Unsymmetrical Disulfides
Тип публикации: Journal Article
Дата публикации: 2021-05-01
SCImago Q1
WOS Q2
БС1
SJR: 0.729
CiteScore: 6
Impact factor: 3.5
ISSN: 00134651, 19457111
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Renewable Energy, Sustainability and the Environment
Краткое описание
A number of substituted o-aminophenols has been investigated as redox mediators of the thiol oxidation to disulfides. The electrooxidation of o-aminophenols leads to the corresponding o-iminobenzoquinones. These compounds react with thiols in the solution with a formation of disulfides. It was established that the use of 4,6-di-tert-butyl-2-(tert-butylamino)phenol as a redox mediator can reduce the overpotential of the thiol oxidation by 0.2–1.4 V depending on the nature of the coupling thiols. The unsymmetrical disulfides with alkyl, aryl, and heteroaryl substituents were obtained as the result of the indirect electrosynthesis.
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Burmistrova D. A. et al. Substituted o-Aminophenols as Redox-Mediators in the Thiol Oxidation to Unsymmetrical Disulfides // Journal of the Electrochemical Society. 2021. Vol. 168. No. 5. p. 55501.
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Burmistrova D. A., Galustyan A., Smolyaninov I. V., Berberova N. T. Substituted o-Aminophenols as Redox-Mediators in the Thiol Oxidation to Unsymmetrical Disulfides // Journal of the Electrochemical Society. 2021. Vol. 168. No. 5. p. 55501.
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TY - JOUR
DO - 10.1149/1945-7111/abfe43
UR - https://iopscience.iop.org/article/10.1149/1945-7111/abfe43
TI - Substituted o-Aminophenols as Redox-Mediators in the Thiol Oxidation to Unsymmetrical Disulfides
T2 - Journal of the Electrochemical Society
AU - Burmistrova, Daria A.
AU - Galustyan, Andrey
AU - Smolyaninov, Ivan V.
AU - Berberova, N. T.
PY - 2021
DA - 2021/05/01
PB - The Electrochemical Society
SP - 55501
IS - 5
VL - 168
SN - 0013-4651
SN - 1945-7111
ER -
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@article{2021_Burmistrova,
author = {Daria A. Burmistrova and Andrey Galustyan and Ivan V. Smolyaninov and N. T. Berberova},
title = {Substituted o-Aminophenols as Redox-Mediators in the Thiol Oxidation to Unsymmetrical Disulfides},
journal = {Journal of the Electrochemical Society},
year = {2021},
volume = {168},
publisher = {The Electrochemical Society},
month = {may},
url = {https://iopscience.iop.org/article/10.1149/1945-7111/abfe43},
number = {5},
pages = {55501},
doi = {10.1149/1945-7111/abfe43}
}
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Burmistrova, Daria A., et al. “Substituted o-Aminophenols as Redox-Mediators in the Thiol Oxidation to Unsymmetrical Disulfides.” Journal of the Electrochemical Society, vol. 168, no. 5, May. 2021, p. 55501. https://iopscience.iop.org/article/10.1149/1945-7111/abfe43.
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