Journal of Chemical Research, volume 45, issue 1-2, pages 42-48
Synthesis, spectroscopic properties, crystal structures, DFT studies, and the antibacterial and enzyme inhibitory properties of a complex of Co(II) 3,5-difluorobenzoate with 3-pyridinol
Publication type: Journal Article
Publication date: 2020-06-03
Journal:
Journal of Chemical Research
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor: 1.4
ISSN: 03082342, 17475198, 20476507
General Chemistry
Abstract
A new complex, [Co(DFB)2(3-Pyr)2(H2O)2] (where DFB = 3,5-difluorobenzoate, 3-Pyr = 3-pyridinol), is synthesized and characterized using different techniques (elemental analysis, Fourier transform infrared spectroscopy, and single-crystal X-ray diffraction). Looking at the crystal structure of the complexes, the cobalt atom is coordinated by two nitrogen atoms from two 3-Pyr ligands, two carboxylate oxygen atoms from two DFB anions, and two oxygen atoms from two water molecules. The complex has distorted octahedral geometry around the cobalt atom center complex and crystallizes in the P21/n space group (monoclinic system). Geometry optimization, frequency analysis, and energy quantum chemical calculations on the complex are performed by Density Functional Theory [B3LYP/6-31G (d,p) basis set] to predict the molecular properties. The novel complex is tested against the metabolic isoenzymes human carbonic anhydrases I and II. The novel complex shows Ki values of 317.26 ± 23.25 µM against hCA I and 255.41 ± 48.05 µM against hCA II; the IC50 values for these isoenzymes are 274.37 and 204.33 µM.
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Sertçelik M. Synthesis, spectroscopic properties, crystal structures, DFT studies, and the antibacterial and enzyme inhibitory properties of a complex of Co(II) 3,5-difluorobenzoate with 3-pyridinol // Journal of Chemical Research. 2020. Vol. 45. No. 1-2. pp. 42-48.
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Sertçelik M. Synthesis, spectroscopic properties, crystal structures, DFT studies, and the antibacterial and enzyme inhibitory properties of a complex of Co(II) 3,5-difluorobenzoate with 3-pyridinol // Journal of Chemical Research. 2020. Vol. 45. No. 1-2. pp. 42-48.
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TY - JOUR
DO - 10.1177/1747519820924636
UR - https://doi.org/10.1177/1747519820924636
TI - Synthesis, spectroscopic properties, crystal structures, DFT studies, and the antibacterial and enzyme inhibitory properties of a complex of Co(II) 3,5-difluorobenzoate with 3-pyridinol
T2 - Journal of Chemical Research
AU - Sertçelik, Mustafa
PY - 2020
DA - 2020/06/03 00:00:00
PB - SAGE
SP - 42-48
IS - 1-2
VL - 45
SN - 0308-2342
SN - 1747-5198
SN - 2047-6507
ER -
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@article{2020_Sertçelik,
author = {Mustafa Sertçelik},
title = {Synthesis, spectroscopic properties, crystal structures, DFT studies, and the antibacterial and enzyme inhibitory properties of a complex of Co(II) 3,5-difluorobenzoate with 3-pyridinol},
journal = {Journal of Chemical Research},
year = {2020},
volume = {45},
publisher = {SAGE},
month = {jun},
url = {https://doi.org/10.1177/1747519820924636},
number = {1-2},
pages = {42--48},
doi = {10.1177/1747519820924636}
}
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Sertçelik, Mustafa. “Synthesis, spectroscopic properties, crystal structures, DFT studies, and the antibacterial and enzyme inhibitory properties of a complex of Co(II) 3,5-difluorobenzoate with 3-pyridinol.” Journal of Chemical Research, vol. 45, no. 1-2, Jun. 2020, pp. 42-48. https://doi.org/10.1177/1747519820924636.