Bulletin of the Chemical Society of Japan, volume 46, issue 3, pages 888-892

The Synthesis and Absolute Configuration of Optically Active Tricyclo[4.3.0.03,8]nonane (Twist-brendane)

Koichiro Naemura
Masao NAKAZAKI
Publication typeJournal Article
Publication date1973-03-01
scimago Q2
SJR0.665
CiteScore6.4
Impact factor3.3
ISSN00092673, 13480634
General Chemistry
Abstract
(−)-Tricyclo[4.3.0.03,8]nonane (“twist-brendane”) was synthesized via (−)-tricyclo[4.3.0.03,8]nonan-2-one (“twist-brendan-2-one”). The absolute configuration, (1R,3S,6S,8R)-tricyclo[4.3.0.03,8]nonane was assigned to (−)-twist-brendane by correlating with (−)-endo-5-carboxybicyclo[2.2.1]heptane.
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