volume 58 issue 6 pages 1867-1868

Preparation of Hexafluorodisilane and Reactions of Hexafluorodisilane and Hexachlorodisilane with Sulfur Trioxide

Bettadapura Srinivasaiah Suresh
Doddaballapur Krishnamurthy Padma
Publication typeJournal Article
Publication date1985-06-01
scimago Q2
wos Q2
SJR0.678
CiteScore7.0
Impact factor3.8
ISSN00092673, 13480634
General Chemistry
Abstract
Hexafluorodisilane has been prepared by the fluorination of hexachlorodisilane or hexabromodisilane by potassium fluoride in boiling acetonitrile, in yields approximating 45 and 60% respectively. Hexafluorodisilane has been characterised by infrared spectral data, vapour density measurements and analytical data. Both hexafluorodisilane and hexachlorodisilane are found to react with sulfur trioxide when heated to 400°C for 12 h. The products of reaction are silicon tetrafluoride, silica and sulfur dioxide with hexafluorodisilane while hexachlorodisilane in addition gives rise to hexachlorodisiloxane.
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GOST Copy
Suresh B. S., Padma D. K. Preparation of Hexafluorodisilane and Reactions of Hexafluorodisilane and Hexachlorodisilane with Sulfur Trioxide // Bulletin of the Chemical Society of Japan. 1985. Vol. 58. No. 6. pp. 1867-1868.
GOST all authors (up to 50) Copy
Suresh B. S., Padma D. K. Preparation of Hexafluorodisilane and Reactions of Hexafluorodisilane and Hexachlorodisilane with Sulfur Trioxide // Bulletin of the Chemical Society of Japan. 1985. Vol. 58. No. 6. pp. 1867-1868.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1246/bcsj.58.1867
UR - https://doi.org/10.1246/bcsj.58.1867
TI - Preparation of Hexafluorodisilane and Reactions of Hexafluorodisilane and Hexachlorodisilane with Sulfur Trioxide
T2 - Bulletin of the Chemical Society of Japan
AU - Suresh, Bettadapura Srinivasaiah
AU - Padma, Doddaballapur Krishnamurthy
PY - 1985
DA - 1985/06/01
PB - Oxford University Press
SP - 1867-1868
IS - 6
VL - 58
SN - 0009-2673
SN - 1348-0634
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1985_Suresh,
author = {Bettadapura Srinivasaiah Suresh and Doddaballapur Krishnamurthy Padma},
title = {Preparation of Hexafluorodisilane and Reactions of Hexafluorodisilane and Hexachlorodisilane with Sulfur Trioxide},
journal = {Bulletin of the Chemical Society of Japan},
year = {1985},
volume = {58},
publisher = {Oxford University Press},
month = {jun},
url = {https://doi.org/10.1246/bcsj.58.1867},
number = {6},
pages = {1867--1868},
doi = {10.1246/bcsj.58.1867}
}
MLA
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MLA Copy
Suresh, Bettadapura Srinivasaiah, and Doddaballapur Krishnamurthy Padma. “Preparation of Hexafluorodisilane and Reactions of Hexafluorodisilane and Hexachlorodisilane with Sulfur Trioxide.” Bulletin of the Chemical Society of Japan, vol. 58, no. 6, Jun. 1985, pp. 1867-1868. https://doi.org/10.1246/bcsj.58.1867.