Asymmetric Reduction ofβ-Keto Esters with an Enzyme from Bakers’ Yeast
Publication type: Journal Article
Publication date: 1994-03-01
scimago Q2
wos Q2
SJR: 0.678
CiteScore: 7.0
Impact factor: 3.8
ISSN: 00092673, 13480634
General Chemistry
Abstract
Various β-keto esters have been reduced by one of β-keto ester reductases isolated from bakers’ yeast. The corresponding β-hydroxy esters have been obtained in excellent enantiomeric and diastereomeric excesses, respectively. It has also been elucidated that the reductase recognizes the stereochemistry not only at the β-carbon but also at the α-carbon affording one of the four possible diastereoisomers of α-substituted β-hydroxy esters predominantly. The stereoselectivity is excellent and chemical yields are moderate to good.
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Kawai Y. et al. Asymmetric Reduction ofβ-Keto Esters with an Enzyme from Bakers’ Yeast // Bulletin of the Chemical Society of Japan. 1994. Vol. 67. No. 2. pp. 524-528.
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Kawai Y., Tsujimoto M., Kondo S., Takanobe K., Kaoru N., Ohno A. Asymmetric Reduction ofβ-Keto Esters with an Enzyme from Bakers’ Yeast // Bulletin of the Chemical Society of Japan. 1994. Vol. 67. No. 2. pp. 524-528.
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RIS
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TY - JOUR
DO - 10.1246/bcsj.67.524
UR - https://doi.org/10.1246/bcsj.67.524
TI - Asymmetric Reduction ofβ-Keto Esters with an Enzyme from Bakers’ Yeast
T2 - Bulletin of the Chemical Society of Japan
AU - Kawai, Yasushi
AU - Tsujimoto, Munekazu
AU - Kondo, Shin-ichi
AU - Takanobe, Kousuke
AU - Kaoru, Nakamura
AU - Ohno, Atsuyoshi
PY - 1994
DA - 1994/03/01
PB - Oxford University Press
SP - 524-528
IS - 2
VL - 67
SN - 0009-2673
SN - 1348-0634
ER -
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BibTex (up to 50 authors)
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@article{1994_Kawai,
author = {Yasushi Kawai and Munekazu Tsujimoto and Shin-ichi Kondo and Kousuke Takanobe and Nakamura Kaoru and Atsuyoshi Ohno},
title = {Asymmetric Reduction ofβ-Keto Esters with an Enzyme from Bakers’ Yeast},
journal = {Bulletin of the Chemical Society of Japan},
year = {1994},
volume = {67},
publisher = {Oxford University Press},
month = {mar},
url = {https://doi.org/10.1246/bcsj.67.524},
number = {2},
pages = {524--528},
doi = {10.1246/bcsj.67.524}
}
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MLA
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Kawai, Yasushi, et al. “Asymmetric Reduction ofβ-Keto Esters with an Enzyme from Bakers’ Yeast.” Bulletin of the Chemical Society of Japan, vol. 67, no. 2, Mar. 1994, pp. 524-528. https://doi.org/10.1246/bcsj.67.524.